Electron-Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules

被引：0

作者：

Purtov, P. A. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Voevodsky Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

HIGH ENERGY CHEMISTRY | 2023年 / 57卷 / SUPPL 3期

关键词：

photochemical decomposition; spin polarization; spin alignment; radical pair; density matrix; Zeeman interaction; hyperfine interaction; GREEN-FUNCTION METHOD; SPIN POLARIZATION; APPROXIMATION; ZERO;

D O I：

10.1134/S001814392309014X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Calculations of electron-nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.

引用

页码：S460 / S463

页数：4

共 5 条

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