Potential of epoxy coating containing ionic liquid as anti-corrosion coating: Evaluation of barrier properties

被引:8
|
作者
Marcelin, Sabrina [1 ]
Livi, Sebastien [2 ]
Ter-Ovanessian, Benoit [1 ]
Tribollet, Bernard [3 ]
Mary, Nicolas [1 ,4 ]
Normand, Bernard [1 ]
机构
[1] Univ Lyon, INSA LYON, MATEIS UMR 5510, CNRS, 7 Ave Jean Capelle, F-69621 Villeurbanne, France
[2] Univ Lyon, INSA LYON, IMP UMR CNRS 5223, Bat Jules Verne, 17 Ave Jean Capelle, F-69621 Villeurbanne, France
[3] Sorbonne Univ, Fac Sci & Ingn, Lab Interfaces & Syst Electrochim LISE, CNRS,UMR 8235, 4 Pl Jussieu, F-75005 Paris, France
[4] Tohoku Univ, Univ Lyon, Mat Solut Ctr, CNRS,ElytMax UMI 3757, Room 502,2-1-1 Katahira,Aoba Ku, Sendai 9808577, Japan
来源
关键词
Epoxy coating; Ionic liquid; Electrochemical impedance spectroscopy; RESISTIVITY DISTRIBUTIONS; CORROSION PROTECTION; SURFACE-TENSION; PHYSICAL-PROPERTIES; CARBON-STEEL; BEHAVIOR; PERMEABILITY; TEMPERATURE; IMPROVEMENT; NETWORKS;
D O I
10.1016/j.surfcoat.2024.130376
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Barrier properties of innovative epoxy coatings containing 10 or 20 phr of phosphate/phosphonium ionic liquid (IL) were investigated using mainly electrochemical impedance spectroscopy. The impedance diagrams revealed quasi-pure capacitive behavior and the impedance modulus at low frequency, related to corrosion resistance, remains at around 1012 omega cm2 during immersion time in 0.1 M NaCl solution. The capacitances were graphically extracted from Cole-Cole representations, and the resistances were determined using R//C electric equivalent circuits. Both epoxy-IL coatings were free of porosity and impeded the hydration of the matrix. The results were also compared to those of conventional epoxy coatings, for which hydration occurs owing to their porosity. Results indicate that this new epoxy-IL coating system would offer excellent anticorrosion protection for metallic substrates.
引用
收藏
页数:9
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