Asymmetric Catalytic Approaches Employing α,β-Unsaturated Imines

被引:14
作者
Saha, Suman K. [1 ]
Bera, Anupriya [1 ]
Singh, Soniya [1 ]
Rana, Nirmal K. [1 ]
机构
[1] Indian Inst Technol Jodhpur, Dept Chem, Jodhpur 342030, Rajasthan, India
关键词
Asymmetric catalysis; Conjugated imines; Heterocycles; Metal-catalysis; Organocatalysis; DIELS-ALDER REACTIONS; BAYLIS-HILLMAN CARBONATES; ENANTIOSELECTIVE 4+2 CYCLOADDITION; DOUBLE NUCLEOPHILIC-ADDITION; CYCLIC; 1-AZADIENES; MICHAEL ADDITION; SPIROCYCLIC OXINDOLES; CONJUGATE ADDITION; IN-SITU; ANNULATION;
D O I
10.1002/ejoc.202201470
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Nitrogen-containing heterocyclic compounds have consistently been a noticeable center of attention due to their significant utilization in the domain of synthetic organic chemistry, agrochemicals, and pharmaceuticals. alpha,beta-Unsaturated imines or conjugated imines provide a lot of significant cyclic as well as acyclic products through reacting with a versatile family of compounds. This review summarizes the recent advances in enantioselective reactions of alpha,beta-unsaturated imines by using synthetic methodologies for synthesizing various nitrogen-containing heterocycles that contain four to six-membered rings. The synthesis of rarely found seven-, eight- and nine-membered nitrogen-containing heterocycles have also been reported.
引用
收藏
页数:52
相关论文
共 121 条
[1]  
Abdel-Magid A.F., 2014, Compr.Org. Synth, V2nd, P85, DOI DOI 10.1016/B978-0-08-097742-3.00802-8
[2]   The Construction of 3-Methyl-4-arylpiperidines via a trans-Perhydroindolic Acid-Catalyzed Asymmetric Aza-Diels-Alder Reaction [J].
An, Qianjin ;
Shen, Jiefeng ;
Butt, Nicholas ;
Liu, Delong ;
Liu, Yangang ;
Zhang, Wanbin .
ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (16-17) :3627-3638
[3]  
[Anonymous], 2020, ANGEW CHEM, V132, P1259
[4]  
[Anonymous], 2009, ANGEW CHEM INT EDIT, V48, P5474
[5]  
[Anonymous], 2017, ANGEW CHEM, V129, P14410
[6]  
[Anonymous], 2021, ANGEW CHEM, V133, P5870
[7]  
[Anonymous], 2012, ANGEW CHEM, V124, P12496
[8]  
[Anonymous], 2008, ANGEW CHEM, V120, P10119
[9]  
[Anonymous], 2020, ANGEW CHEM, V132, P2762
[10]  
[Anonymous], 2020, ANGEW CHEM, V132, P19147