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Design and preparation of novel Y2O3-SiO2 composite aerogels for high-temperature thermal insulators
被引:9
|作者:
Ren, Yuhan
[1
]
Zhang, Biao
[1
]
Ye, Jian
[1
]
Zhang, Haoqian
[1
]
Zhong, Zhaoxin
[1
]
Wang, Yang
[1
]
Ye, Feng
[1
]
机构:
[1] Harbin Inst Technol, Inst Adv Ceram, Sch Mat Sci & Engn, Harbin 150080, Peoples R China
关键词:
Y2O3-SiO2;
Aerogels;
High-temperature thermal insulators;
Y-Si molar ratios;
METAL-OXIDE AEROGELS;
CARBON AEROGELS;
INORGANIC SALT;
CONDUCTIVITY;
STABILITY;
AREA;
D O I:
10.1016/j.jnoncrysol.2023.122177
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
This study successfully prepared a series of novel Y2O3-SiO2 composite aerogels using sol-gel methods. The high-temperature calcined SiO2-poor aerogels exhibit excellent high-temperature thermal stability in terms of shrinkage, porosity, and BET surface area maintenance. SiO2-rich aerogels exhibit more pronounced mesoporous material properties, the BET surface area and pore volume of sample Y2S1 reached 291.04 m(2)/g and 0.50 cm(3)/g, an increase of 278.71% and 297.78% over the pure Y2O3 aerogel, respectively. In addition, compared with untreated mullite fiber, the thermal conductivity of the mullite fiber after impregnation with Y2O3-SiO2 composite aerogels decreased by 35.32-45.77% at 300 degrees C, which is similar to the performance of impregnation with Al2O3-SiO2 composite aerogel (38.31%). Moreover, the Y2O3-SiO2 composite aerogel with a high BET surface area may have potential applications in the field of luminescent materials such as phosphors due to the intrinsic electronic structure of the rare-earth yttrium and its fantastic optical properties.
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页数:10
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