Design and preparation of novel Y2O3-SiO2 composite aerogels for high-temperature thermal insulators

被引:10
作者
Ren, Yuhan [1 ]
Zhang, Biao [1 ]
Ye, Jian [1 ]
Zhang, Haoqian [1 ]
Zhong, Zhaoxin [1 ]
Wang, Yang [1 ]
Ye, Feng [1 ]
机构
[1] Harbin Inst Technol, Inst Adv Ceram, Sch Mat Sci & Engn, Harbin 150080, Peoples R China
关键词
Y2O3-SiO2; Aerogels; High-temperature thermal insulators; Y-Si molar ratios; METAL-OXIDE AEROGELS; CARBON AEROGELS; INORGANIC SALT; CONDUCTIVITY; STABILITY; AREA;
D O I
10.1016/j.jnoncrysol.2023.122177
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This study successfully prepared a series of novel Y2O3-SiO2 composite aerogels using sol-gel methods. The high-temperature calcined SiO2-poor aerogels exhibit excellent high-temperature thermal stability in terms of shrinkage, porosity, and BET surface area maintenance. SiO2-rich aerogels exhibit more pronounced mesoporous material properties, the BET surface area and pore volume of sample Y2S1 reached 291.04 m(2)/g and 0.50 cm(3)/g, an increase of 278.71% and 297.78% over the pure Y2O3 aerogel, respectively. In addition, compared with untreated mullite fiber, the thermal conductivity of the mullite fiber after impregnation with Y2O3-SiO2 composite aerogels decreased by 35.32-45.77% at 300 degrees C, which is similar to the performance of impregnation with Al2O3-SiO2 composite aerogel (38.31%). Moreover, the Y2O3-SiO2 composite aerogel with a high BET surface area may have potential applications in the field of luminescent materials such as phosphors due to the intrinsic electronic structure of the rare-earth yttrium and its fantastic optical properties.
引用
收藏
页数:10
相关论文
共 40 条
[1]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[2]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[3]   Preparation and characterization of monolithic Al2O3-SiO2 aerogel [J].
Chen, Heng ;
Sui, Xueye ;
Zhou, Changling ;
Wang, Chonghai ;
Liu, Futian .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2016, 124 (04) :442-447
[4]   Aerogel synthesis of yttria-stabilized zirconia by a non-alkoxide sol-gel route [J].
Chervin, CN ;
Clapsaddle, BJ ;
Chiu, HW ;
Gash, AE ;
Satcher, JH ;
Kauzlarich, SM .
CHEMISTRY OF MATERIALS, 2005, 17 (13) :3345-3351
[5]   Rare earth lanthanum based aerogels with reduced chlorine ions by a modified epoxide gelation method [J].
Chu, Wei ;
Guo, Sipeng ;
Zhang, Jing ;
Liu, Xiaochan ;
Zhao, Xinfu ;
Yi, Xibin ;
Liu, Benxue .
CHEMICAL PHYSICS LETTERS, 2020, 761
[6]   Fabrication and microstructure evolution of monolithic bridged polysilsesquioxane-derived SiC ceramic aerogels [J].
Ding, Chengxi ;
Hu, Dongxiao ;
He, Xinrui ;
Lai, Yifan ;
Shao, Gaofeng .
CERAMICS INTERNATIONAL, 2022, 48 (18) :25833-25839
[7]   Synthesis and textural evolution of mesoporous Si3N4 aerogel with high specific surface area and excellent thermal insulation property via the urea assisted sol-gel technique [J].
Ding, Jie ;
Wu, Xiaodong ;
Shen, Xiaodong ;
Cui, Sheng ;
Zhong, Ya ;
An, Chen ;
Cui, Yi ;
Chen, Xiangbao .
CHEMICAL ENGINEERING JOURNAL, 2020, 382
[8]   Ultralow density carbon aerogels with low thermal conductivity up to 2000 °C [J].
Feng, Junzong ;
Feng, Jian ;
Jiang, Yonggang ;
Zhang, Changrui .
MATERIALS LETTERS, 2011, 65 (23-24) :3454-3456
[9]   New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors [J].
Gash, AE ;
Tillotson, TM ;
Satcher, JH ;
Hrubesh, LW ;
Simpson, RL .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 285 (1-3) :22-28
[10]   Use of epoxides in the sol-gel synthesis of porous iron(III) oxide monoliths from Fe(III) salts [J].
Gash, AE ;
Tillotson, TM ;
Satcher, JH ;
Poco, JF ;
Hrubesh, LW ;
Simpson, RL .
CHEMISTRY OF MATERIALS, 2001, 13 (03) :999-1007