Design and preparation of novel Y2O3-SiO2 composite aerogels for high-temperature thermal insulators

被引:9
|
作者
Ren, Yuhan [1 ]
Zhang, Biao [1 ]
Ye, Jian [1 ]
Zhang, Haoqian [1 ]
Zhong, Zhaoxin [1 ]
Wang, Yang [1 ]
Ye, Feng [1 ]
机构
[1] Harbin Inst Technol, Inst Adv Ceram, Sch Mat Sci & Engn, Harbin 150080, Peoples R China
关键词
Y2O3-SiO2; Aerogels; High-temperature thermal insulators; Y-Si molar ratios; METAL-OXIDE AEROGELS; CARBON AEROGELS; INORGANIC SALT; CONDUCTIVITY; STABILITY; AREA;
D O I
10.1016/j.jnoncrysol.2023.122177
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This study successfully prepared a series of novel Y2O3-SiO2 composite aerogels using sol-gel methods. The high-temperature calcined SiO2-poor aerogels exhibit excellent high-temperature thermal stability in terms of shrinkage, porosity, and BET surface area maintenance. SiO2-rich aerogels exhibit more pronounced mesoporous material properties, the BET surface area and pore volume of sample Y2S1 reached 291.04 m(2)/g and 0.50 cm(3)/g, an increase of 278.71% and 297.78% over the pure Y2O3 aerogel, respectively. In addition, compared with untreated mullite fiber, the thermal conductivity of the mullite fiber after impregnation with Y2O3-SiO2 composite aerogels decreased by 35.32-45.77% at 300 degrees C, which is similar to the performance of impregnation with Al2O3-SiO2 composite aerogel (38.31%). Moreover, the Y2O3-SiO2 composite aerogel with a high BET surface area may have potential applications in the field of luminescent materials such as phosphors due to the intrinsic electronic structure of the rare-earth yttrium and its fantastic optical properties.
引用
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页数:10
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