Phase engineering of Ni-Mn binary layered oxide cathodes for sodium-ion batteries

被引：22
作者：
Hong, Feifei [1 ]
Zhou, Xin [2 ]
Liu, Xiaohong [1 ]
Feng, Guilin [3 ,4 ]
Zhang, Heng [5 ]
Fan, Weifeng [6 ]
Zhang, Bin [6 ]
Zuo, Meihua [6 ]
Xing, Wangyan [6 ]
Zhang, Ping [6 ]
Yan, Hua [7 ]
Xiang, Wei [1 ]
机构：
[1] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, Chengdu 610059, Sichuan, Peoples R China
[2] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Sichuan, Peoples R China
[3] Hokkaido Univ, Res Inst Elect Sci RIES, N20W10, Sapporo, Hokkaido 0010020, Japan
[4] Hokkaido Univ, Grad Sch Informat Sci & Technol, Div Informat Sci & Technol, N20W10, Sapporo, Hokkaido 0010020, Japan
[5] Suzhou Univ Sci & Technol, Sch Mat Sci & Engn, Suzhou 215009, Jiangsu, Peoples R China
[6] Yibin Libode New Mat Co Ltd, Yibin 644200, Sichuan, Peoples R China
[7] Cent South Univ, Engn Res Ctr, Sch Met & Environm, Minist Educ Adv Battery Mat, Changsha 410083, Hunan, Peoples R China
来源：
JOURNAL OF ENERGY CHEMISTRY | 2024年 / 91卷
基金：
中国国家自然科学基金;
关键词：
Phase engineering; Ni-Mn layered oxide; Cathode; Sodium-ion batteries; HIGH-PERFORMANCE;
D O I：
10.1016/j.jechem.2024.01.025
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Nickel-manganese binary layered oxides with high working potential and low cost are potential candidates for sodium-ion batteries, but their electrochemical properties are highly related to compositional diversity. Diverse composite materials with various phase structures of P3, P2/P3, P2, P2/O3, and P2/ P3/O3 were synthesized by manipulating the sodium content and calcination conditions, leading to the construction of a synthetic phase diagram for NaxNi0.25Mn0.75O2 (0.45 <= x <= 1.1). Then, we compared the electrochemical characteristics and structural evolution during the desodiation/sodiation process of P2, P2/P3, P2/O3, and P2/P3/O3-NaxNi0.25Mn0.75O2. Among them, P2/P3-Na0.75Ni0.25Mn0.75O2 exhibits the best rate capability of 90.9 mA h g at 5 C, with an initial discharge capacity of 142.62 mA h g-1 at 0.1 C and a capacity retention rate of 78.25% after 100 cycles at 1 C in the voltage range of 2-4.3 V. The observed superior sodium storage performance of P2/P3 hybrids compared to other composite phases can be attributed to the enhanced Na' transfer dynamic, reduction of the Jahn-teller effect, and improved reaction reversibility induced by the synergistic effect of P2 and P3 phases. The systematic research and exploration of phases in NaxNi0.25Mn0.75O2 provide new sights into high-performance nickel-manganese binary layered oxide for sodium-ion batteries. (c) 2024 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
引用
收藏
页码：501 / 511
页数：11
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