Phase engineering of Ni-Mn binary layered oxide cathodes for sodium-ion batteries

被引：23

作者：

Hong, Feifei ^{[1
]}

Zhou, Xin ^{[2
]}

Liu, Xiaohong ^{[1
]}

Feng, Guilin ^{[3
,4
]}

Zhang, Heng ^{[5
]}

Fan, Weifeng ^{[6
]}

Zhang, Bin ^{[6
]}

Zuo, Meihua ^{[6
]}

Xing, Wangyan ^{[6
]}

Zhang, Ping ^{[6
]}

Yan, Hua ^{[7
]}

Xiang, Wei ^{[1
]}

机构：

[1] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, Chengdu 610059, Sichuan, Peoples R China

[2] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Sichuan, Peoples R China

[3] Hokkaido Univ, Res Inst Elect Sci RIES, N20W10, Sapporo, Hokkaido 0010020, Japan

[4] Hokkaido Univ, Grad Sch Informat Sci & Technol, Div Informat Sci & Technol, N20W10, Sapporo, Hokkaido 0010020, Japan

[5] Suzhou Univ Sci & Technol, Sch Mat Sci & Engn, Suzhou 215009, Jiangsu, Peoples R China

[6] Yibin Libode New Mat Co Ltd, Yibin 644200, Sichuan, Peoples R China

[7] Cent South Univ, Engn Res Ctr, Sch Met & Environm, Minist Educ Adv Battery Mat, Changsha 410083, Hunan, Peoples R China

来源：

JOURNAL OF ENERGY CHEMISTRY | 2024年 / 91卷

基金：

中国国家自然科学基金;

关键词：

Phase engineering; Ni-Mn layered oxide; Cathode; Sodium-ion batteries; HIGH-PERFORMANCE;

D O I：

10.1016/j.jechem.2024.01.025

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Nickel-manganese binary layered oxides with high working potential and low cost are potential candidates for sodium-ion batteries, but their electrochemical properties are highly related to compositional diversity. Diverse composite materials with various phase structures of P3, P2/P3, P2, P2/O3, and P2/ P3/O3 were synthesized by manipulating the sodium content and calcination conditions, leading to the construction of a synthetic phase diagram for NaxNi0.25Mn0.75O2 (0.45 <= x <= 1.1). Then, we compared the electrochemical characteristics and structural evolution during the desodiation/sodiation process of P2, P2/P3, P2/O3, and P2/P3/O3-NaxNi0.25Mn0.75O2. Among them, P2/P3-Na0.75Ni0.25Mn0.75O2 exhibits the best rate capability of 90.9 mA h g at 5 C, with an initial discharge capacity of 142.62 mA h g-1 at 0.1 C and a capacity retention rate of 78.25% after 100 cycles at 1 C in the voltage range of 2-4.3 V. The observed superior sodium storage performance of P2/P3 hybrids compared to other composite phases can be attributed to the enhanced Na' transfer dynamic, reduction of the Jahn-teller effect, and improved reaction reversibility induced by the synergistic effect of P2 and P3 phases. The systematic research and exploration of phases in NaxNi0.25Mn0.75O2 provide new sights into high-performance nickel-manganese binary layered oxide for sodium-ion batteries. (c) 2024 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.

引用

页码：501 / 511

页数：11

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