Alkylation of furancarboxylic acid derivatives with alkenes catalyzed by nickel complexes with N-heterocyclic carbenes

被引：2

作者：

Shepelenko, K. E. ^{[1
]}

Soliev, S. B. ^{[1
]}

Nikolaeva, K. A. ^{[1
]}

Minyaev, M. E. ^{[2
]}

Chernyshev, V. M. ^{[1
]}

机构：

[1] MI Platov South Russian State Polytech Univ NPI, 132 Ul Prosveshcheniya, Novocherkassk 346428, Russia

[2] Russian Acad Sci, N D Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 08期

关键词：

nickel; furans; N-heterocyclic carbenes; CH-alkylation; catalysis; DIRECT ARYLATION; 2,5-FURANDICARBOXYLIC ACID; RECENT PROGRESS; FURANS; FUNCTIONALIZATION; CONVERSION; POLYMERS;

D O I：

10.1007/s11172-023-3956-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient catalytic system based on commercially available nickel source (NiCp2), N-heterocyclic carbene, and a reducing agent (HCOONa) for selective C(5)H-alkylation of amides and esters of 2-furancarboxylic acid with alkenes of various structures was developed. A series of new previously undescribed 5-alkyl derivatives of 2-furancarboxylic acid were synthesized.

引用

页码：1746 / 1752

页数：7

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