Usability of brass and stainless steel electrodes in electrochemical treatment of 4-nitrophenol

被引:7
|
作者
Simsek, Ismail [1 ]
机构
[1] Aksaray Univ, Dept Environm Engn, TR-68100 Aksaray, Turkiye
来源
JOURNAL OF HAZARDOUS MATERIALS ADVANCES | 2023年 / 9卷
关键词
4-Nitrophenol; Electrochemical treatment; Brass electrode; Stainless steel electrode; Statistical analysis; ELECTROCOAGULATION PROCESS; AQUEOUS-SOLUTIONS; WATER-TREATMENT; REMOVAL; ELECTROOXIDATION; OXIDATION; OPTIMIZATION; NITROPHENOLS; RECOVERY; ANODE;
D O I
10.1016/j.hazadv.2023.100249
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
4-Nitrophenol (4NP), which is used in many industries, is among the priority pollutants due to its carcinogenic, teratogenic, and mutagenic effects. In this study, the treatment of an aqueous solution containing 4NP was carried out by electrochemical method. A stainless steel electrode (Ss) allowing both electro-oxidation and electrocoag-ulation to occur together was used at the anode, while a brass (Bs) electrode with high conductivity was used at the cathode. By performing 4NP and total organic carbon (TOC) analyses on the samples taken from the re-actor at certain times, the removal efficiencies and mineralization current efficiency (MCE) were determined. Based on the results, the optimum values of the operating parameters affecting the treatment efficiency were determined, the specific energy consumption (SEC) was calculated and the parameter-based statistical analysis of the data was performed. Under optimum conditions (pH: 5.5; Electrolyte: 3 g/L NaCl (5950 & mu;s/cm); Current: 3.0 A (78 mA/cm2); Time: 20 min.; Distance: 0.5 cm), 97.44% 4NP and 33.09% TOC removal efficiencies were obtained. The energy consumption required to treat 1 m 3 of wastewater electrochemically under these condi-tions was calculated as 28.37 kWh/m3. As a result of the statistical analysis, the most effective parameters in electrochemical treatment were determined as current, and time, respectively.
引用
收藏
页数:12
相关论文
共 50 条
  • [41] Degradation of ciprofloxacin by the Electrochemical Peroxidation process using stainless steel electrodes
    Bueno, Francine
    Borba, Fernando H.
    Pellenz, Leandro
    Schmitz, Michely
    Godoi, Benhur
    Espinoza-Quinones, Fernando R.
    de Pauli, Aline Roberta
    Modenes, Aparecido N.
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2018, 6 (02): : 2855 - 2864
  • [42] In situ formed zinc oxide/graphitic carbon nitride nanohybrid for the electrochemical determination of 4-nitrophenol
    Kizhepat Shamsa
    Peter Selvaraj Mary Rajaitha
    Selvaraj Vinoth
    Chinnan Murugan
    Perumal Rameshkumar
    Alagarsamy Pandikumar
    Microchimica Acta, 2020, 187
  • [43] Ratiometric strategy assisted electrochemical detection of 4-nitrophenol in water samples using nanostructured CuO
    Prakasam, Sampathkumar
    Chellamuthu, Dilip Kumar Latha
    Krishnan, Giribabu
    Chinnathambi, Suresh
    JOURNAL OF MATERIALS CHEMISTRY C, 2024, 12 (32) : 12458 - 12467
  • [44] Sensitive electrochemical detection of 4-nitrophenol through Copper doped CeO2 nanoparticles
    Anees A. Ansari
    Manawwer Alam
    Journal of Electroceramics, 2021, 47 : 51 - 59
  • [45] Electrochemical oxidative determination of 4-nitrophenol based on a glassy carbon electrode modified with a hydroxyapatite nanopowder
    Yin, Huanshun
    Zhou, Yunlei
    Ai, Shiyun
    Liu, Xianggang
    Zhu, Lusheng
    Lu, Linan
    MICROCHIMICA ACTA, 2010, 169 (1-2) : 87 - 92
  • [46] Uncapped Silver Nanoclusters as Potential Catalyst for Enhanced Direct-Electrochemical Oxidation of 4-Nitrophenol
    Kalaiyarasi, G. M.
    Elakkiya, R.
    Kundu, M.
    Jin, W.
    Sasidharan, M.
    Maduraiveeran, G.
    JOURNAL OF CLUSTER SCIENCE, 2019, 30 (02) : 393 - 402
  • [47] Uncapped Silver Nanoclusters as Potential Catalyst for Enhanced Direct-Electrochemical Oxidation of 4-Nitrophenol
    G. M. Kalaiyarasi
    R. Elakkiya
    M. Kundu
    W. Jin
    M. Sasidharan
    G. Maduraiveeran
    Journal of Cluster Science, 2019, 30 : 393 - 402
  • [48] Microwave synthesis of reduced graphene oxide decorated with silver nanoparticles for electrochemical determination of 4-nitrophenol
    Noor, An'amt Mohamed
    Rameshkumar, Perumal
    Yusoff, Norazriena
    Ming, Huang Nay
    Sajab, Mohd Shaiful
    CERAMICS INTERNATIONAL, 2016, 42 (16) : 18813 - 18820
  • [49] A facile approach for synthesizing molecularly imprinted graphene for ultrasensitive and selective electrochemical detecting 4-nitrophenol
    Luo, Jing
    Cong, Jiaojiao
    Liu, Jie
    Gao, Yahan
    Liu, Xiaoya
    ANALYTICA CHIMICA ACTA, 2015, 864 : 74 - 84
  • [50] Electrochemical sensing and remediation of 4-nitrophenol using bio-synthesized copper oxide nanoparticles
    Singh, Suman
    Kumar, Nishant
    Kumar, Manish
    Jyoti
    Agarwal, Ajay
    Mizaikoff, Boris
    CHEMICAL ENGINEERING JOURNAL, 2017, 313 : 283 - 292