Usability of brass and stainless steel electrodes in electrochemical treatment of 4-nitrophenol

被引:7
|
作者
Simsek, Ismail [1 ]
机构
[1] Aksaray Univ, Dept Environm Engn, TR-68100 Aksaray, Turkiye
来源
JOURNAL OF HAZARDOUS MATERIALS ADVANCES | 2023年 / 9卷
关键词
4-Nitrophenol; Electrochemical treatment; Brass electrode; Stainless steel electrode; Statistical analysis; ELECTROCOAGULATION PROCESS; AQUEOUS-SOLUTIONS; WATER-TREATMENT; REMOVAL; ELECTROOXIDATION; OXIDATION; OPTIMIZATION; NITROPHENOLS; RECOVERY; ANODE;
D O I
10.1016/j.hazadv.2023.100249
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
4-Nitrophenol (4NP), which is used in many industries, is among the priority pollutants due to its carcinogenic, teratogenic, and mutagenic effects. In this study, the treatment of an aqueous solution containing 4NP was carried out by electrochemical method. A stainless steel electrode (Ss) allowing both electro-oxidation and electrocoag-ulation to occur together was used at the anode, while a brass (Bs) electrode with high conductivity was used at the cathode. By performing 4NP and total organic carbon (TOC) analyses on the samples taken from the re-actor at certain times, the removal efficiencies and mineralization current efficiency (MCE) were determined. Based on the results, the optimum values of the operating parameters affecting the treatment efficiency were determined, the specific energy consumption (SEC) was calculated and the parameter-based statistical analysis of the data was performed. Under optimum conditions (pH: 5.5; Electrolyte: 3 g/L NaCl (5950 & mu;s/cm); Current: 3.0 A (78 mA/cm2); Time: 20 min.; Distance: 0.5 cm), 97.44% 4NP and 33.09% TOC removal efficiencies were obtained. The energy consumption required to treat 1 m 3 of wastewater electrochemically under these condi-tions was calculated as 28.37 kWh/m3. As a result of the statistical analysis, the most effective parameters in electrochemical treatment were determined as current, and time, respectively.
引用
收藏
页数:12
相关论文
共 50 条
  • [1] Sonovoltammetric determination of 4-nitrophenol on diamond electrodes
    Garbellini, Gustavo S.
    Salazar-Banda, Giancarlo R.
    Avaca, Luis A.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2007, 18 (06) : 1095 - 1099
  • [2] Electrochemical Treatment of Nitrite Using Stainless Steel Electrodes
    Nabil S. Abuzaid
    Zakariya Al-Hamouz
    Alaadin A. Bukhari
    Mohamed H. Essa
    Water, Air, and Soil Pollution, 1999, 109 : 429 - 442
  • [3] Electrochemical treatment of nitrite using stainless steel electrodes
    Abuzaid, NS
    Al-Hamouz, Z
    Bukhari, AA
    Essa, MH
    WATER AIR AND SOIL POLLUTION, 1999, 109 (1-4): : 429 - 442
  • [4] Electrochemical treatment of copper cyanide wastewaters using stainless steel electrodes
    Szpyrkowicz, L
    Zilio-Grandi, F
    Kaul, SN
    Rigoni-Stern, S
    WATER SCIENCE AND TECHNOLOGY, 1998, 38 (06) : 261 - 268
  • [5] Electrochemical Study of 4-Nitrophenol at a Modified Carbon Paste Electrode
    María del Mar Cordero-Rando
    Manuel Barea-Zamora
    Juan M. Barberá-Salvador
    Ignacio Naranjo-Rodríguez
    Juan A. Muñoz-Leyva
    José L. Hidalgo-Hidalgo de Cisneros
    Microchimica Acta, 1999, 132 (1) : 7 - 11
  • [6] Intermittent pulse amperometry as an effective electrochemical assay of 4-nitrophenol
    Prempinij, Waswan
    Suginta, Wipa
    Schulte, Albert
    APPLIED PHYSICS LETTERS, 2023, 123 (03)
  • [7] Electrochemical study of 4-nitrophenol at a modified carbon paste electrode
    Cordero-Rando, MD
    Barea-Zamora, M
    Barberá-Salvador, JM
    Naranjo-Rodriguez, I
    Muñoz-Leyva, JA
    de Cisneros, JLHH
    MIKROCHIMICA ACTA, 1999, 132 (01) : 7 - 11
  • [8] Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes
    Pedrosa, VD
    Codognoto, L
    Avaca, LA
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2003, 14 (04) : 530 - 535
  • [9] TREATMENT OF COPPER CYANIDE WASTEWATERS IN ELECTROCHEMICAL BATCH REACTOR WITH STAINLESS STEEL ELECTRODES
    Malinovic, B.
    Pavlovic, M. G.
    Bunic, S.
    JOURNAL OF ENVIRONMENTAL PROTECTION AND ECOLOGY, 2014, 15 (04): : 1574 - 1582
  • [10] Electrochemical Oxidation of 4-Nitroaniline and 4-Nitrophenol at a Glassy Carbon Electrode
    Pfeifer, Rene
    Martinhon, Priscila Tamiasso
    Sousa, Celia
    Nascimento, Marco A. C.
    Moreira, Josino C.
    Barek, Jiri
    XXXV MODERNI ELEKTROCHEMICKE METODY, 2015, : 170 - 174