Anode corrosion in aqueous Zn metal batteries

被引：211
作者：
Cai, Zhao [1 ,2 ]
Wang, Jindi [1 ,3 ]
Sun, Yongming [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Peoples R China
[2] China Univ Geosci Wuhan, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China
[3] Yancheng Teachers Univ, Inst New Energy Chem Storage & Power Sources, Coll Appl Chem & Environm Engn, Yancheng 224000, Peoples R China
来源：
ESCIENCE | 2023年 / 3卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Aqueous batteries; Zn metal anode; Chemical oxidation; Electrochemical hydrogen evolution; Corrosion mechanism; Surface protection; ZINC-ION BATTERIES; CHALLENGES; STRATEGIES; ELECTROLYTES; INTERFACE; INSIGHT;
D O I：
10.1016/j.esci.2023.100093
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Given their low cost and intrinsic safety, aqueous Zn metal batteries (AZMBs) are drawing increasing attention in the field of smart grids and large-scale energy storage. However, the Zn metal anode in aqueous electrolyte suffers from a critical issue, corrosion, which must be fully addressed before the practical implementation of AZMBs. In this perspective, the mechanisms of aqueous Zn metal anode corrosion in both alkaline and neutral electrolytes are compared and discussed. The methods for studying the corrosion processes and the strategies for Zn corrosion protection in AZMBs are also summarized. Finally, some expectations about potential research directions for making corrosion-resistant AZMBs a commercial reality are provided.
引用
收藏
页数：12
相关论文
共 50 条
[31]   In Situ Constructing Coordination Compounds Interphase to Stabilize Zn Metal Anode for High-Performance Aqueous Zn-SeS2 Batteries [J].
Li, Jianbo ;
He, Bin ;
Zhang, Yi ;
Cheng, Zexiao ;
Yuan, Lixia ;
Huang, Yunhui ;
Li, Zhen .
SMALL, 2022, 18 (18)
[32]   Comprehensive Analyses of Aqueous Zn Metal Batteries: Characterization Methods, Simulations, and Theoretical Calculations [J].
Zhang, Long ;
Hou, Yanglong .
ADVANCED ENERGY MATERIALS, 2021, 11 (13)
[33]   Decoupling, quantifying, and restoring aging-induced Zn-anode losses in rechargeable aqueous zinc batteries [J].
Pu, Shengda D. ;
Hu, Bingkun ;
Li, Zixuan ;
Yuan, Yi ;
Gong, Chen ;
Ning, Ziyang ;
Chau, Chloe ;
Yang, Sixie ;
Zhang, Shengming ;
Pi, Liquan ;
Tang, Yuanbo T. ;
Yue, Jili ;
Marrow, T. James ;
Gao, Xiangwen ;
Bruce, Peter G. ;
Robertson, Alex W. .
JOULE, 2023, 7 (02) :366-379
[34]   "Carbon in Metal" Anode with High Processability for Sodium Metal Batteries [J].
Liu, Yukun ;
Liu, Xuyang ;
Zhang, Guohua ;
Shi, Xinyue ;
Zhang, Ping ;
Fan, Yuxin ;
Huang, Yunhui ;
Zhang, Renyuan .
ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (22) :26691-26699
[35]   A dendrite-free Zn anode enabled by PEDOT:PSS/MoS2 electrokinetic channels for aqueous Zn-ion batteries [J].
Wang, Hai ;
Zhao, Qin ;
Li, Weimin ;
Watanabe, Shun ;
Wang, Xiaobo .
NANOSCALE, 2024, 16 (14) :7200-7210
[36]   Favorable Desolvation and Uniform Zn Deposition of Silica Modified Zn Anode for High Performance Aqueous Zn-Ion Batteries [J].
Yuan, Wangsheng ;
Jin, Kai ;
Zou, Shanbao ;
Jin, Yishan ;
He, Yishuang ;
Yuan, Xinhai ;
Han, Peng ;
Fu, Lijun ;
Wu, Yuping .
ADVANCED SCIENCE, 2025,
[37]   Biomimetic Lipid-Bilayer Anode Protection for Long Lifetime Aqueous Zinc-Metal Batteries [J].
Zhao, Yan ;
Ouyang, Mengzheng ;
Wang, Yuetao ;
Qin, Runzhi ;
Zhang, Hao ;
Pan, Wending ;
Leung, Dennis Y. C. ;
Wu, Billy ;
Liu, Xinhua ;
Brandon, Nigel P. ;
Xuan, Jin ;
Pan, Feng ;
Wang, Huizhi .
ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (34)
[38]   A Dual Salt/Dual Solvent Electrolyte Enables Ultrahigh Utilization of Zinc Metal Anode for Aqueous Batteries [J].
Guan, Kailin ;
Chen, Wenshu ;
Yang, Yunting ;
Ye, Fei ;
Hong, Ye ;
Zhang, Jian ;
Gu, Qinfen ;
Wu, Yuping ;
Hu, Linfeng .
ADVANCED MATERIALS, 2024, 36 (38)
[39]   Recent progress of artificial interfacial layers in aqueous Zn metal batteries [J].
Xiong, Peixun ;
Zhang, Ye ;
Zhang, Jingran ;
Ha Baek, Sang ;
Zeng, Lingxing ;
Yao, Yan ;
Park, Ho Seok .
ENERGYCHEM, 2022, 4 (04)
[40]   Mechanism for Zincophilic Sites on Zinc-Metal Anode Hosts in Aqueous Batteries [J].
Xie, Fangxi ;
Li, Huan ;
Wang, Xuesi ;
Zhi, Xing ;
Chao, Dongliang ;
Davey, Kenneth ;
Qiao, Shi-Zhang .
ADVANCED ENERGY MATERIALS, 2021, 11 (09)
12345