Anode corrosion in aqueous Zn metal batteries

被引：278
作者：
Cai, Zhao [1 ,2 ]
Wang, Jindi [1 ,3 ]
Sun, Yongming [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Peoples R China
[2] China Univ Geosci Wuhan, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China
[3] Yancheng Teachers Univ, Inst New Energy Chem Storage & Power Sources, Coll Appl Chem & Environm Engn, Yancheng 224000, Peoples R China
来源：
ESCIENCE | 2023年 / 3卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Aqueous batteries; Zn metal anode; Chemical oxidation; Electrochemical hydrogen evolution; Corrosion mechanism; Surface protection; ZINC-ION BATTERIES; CHALLENGES; STRATEGIES; ELECTROLYTES; INTERFACE; INSIGHT;
D O I：
10.1016/j.esci.2023.100093
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Given their low cost and intrinsic safety, aqueous Zn metal batteries (AZMBs) are drawing increasing attention in the field of smart grids and large-scale energy storage. However, the Zn metal anode in aqueous electrolyte suffers from a critical issue, corrosion, which must be fully addressed before the practical implementation of AZMBs. In this perspective, the mechanisms of aqueous Zn metal anode corrosion in both alkaline and neutral electrolytes are compared and discussed. The methods for studying the corrosion processes and the strategies for Zn corrosion protection in AZMBs are also summarized. Finally, some expectations about potential research directions for making corrosion-resistant AZMBs a commercial reality are provided.
引用
收藏
页数：12
相关论文
共 115 条
[1]   Interfacial parasitic reactions of zinc anodes in zinc ion batteries: Underestimated corrosion and hydrogen evolution reactions and their suppression strategies [J].
Bayaguud, Aruuhan ;
Fu, Yanpeng ;
Zhu, Changbao .
JOURNAL OF ENERGY CHEMISTRY, 2022, 64 (246-262) :246-262
[2]   Cationic Surfactant-Type Electrolyte Additive Enables Three-Dimensional Dendrite-Free Zinc Anode for Stable Zinc-Ion Batteries [J].
Bayaguud, Aruuhan ;
Luo, Xiao ;
Fu, Yanpeng ;
Zhu, Changbao .
ACS ENERGY LETTERS, 2020, 5 (09) :3012-3020
[3]   Scientific Challenges for the Implementation of Zn-Ion Batteries [J].
Blanc, Lauren E. ;
Kundu, Dipan ;
Nazar, Linda F. .
JOULE, 2020, 4 (04) :771-799
[4]   Water-Salt Oligomers Enable Supersoluble Electrolytes for High-Performance Aqueous Batteries [J].
Cai, Shengying ;
Chu, Xingyuan ;
Liu, Chang ;
Lai, Haiwen ;
Chen, Hao ;
Jiang, Yanqiu ;
Guo, Fan ;
Xu, Zhikang ;
Wang, Chunsheng ;
Gao, Chao .
ADVANCED MATERIALS, 2021, 33 (13)
[5]   Ultrafast Metal Electrodeposition Revealed by In Situ Optical Imaging and Theoretical Modeling towards Fast-Charging Zn Battery Chemistry [J].
Cai, Zhao ;
Wang, Jindi ;
Lu, Ziheng ;
Zhan, Renming ;
Ou, Yangtao ;
Wang, Li ;
Dahbi, Mouad ;
Alami, Jones ;
Lu, Jun ;
Amine, Khalil ;
Sun, Yongming .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (14)
[6]   A Replacement Reaction Enabled Interdigitated Metal/Solid Electrolyte Architecture for Battery Cycling at 20 mA cm-2 and 20 mAh cm-2 [J].
Cai, Zhao ;
Ou, Yangtao ;
Zhang, Bao ;
Wang, Jindi ;
Fu, Lin ;
Wan, Mintao ;
Li, Guocheng ;
Wang, Wenyu ;
Wang, Li ;
Jiang, Jianjun ;
Seh, Zhi Wei ;
Hu, Enyuan ;
Yang, Xiao-Qing ;
Cui, Yi ;
Sun, Yongming .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (08) :3143-3152
[7]   Chemically resistant Cu-Zn/Zn composite anode for long cycling aqueous batteries [J].
Cai, Zhao ;
Ou, Yangtao ;
Wang, Jindi ;
Xiao, Run ;
Fu, Lin ;
Yuan, Zhu ;
Zhan, Renmin ;
Sun, Yongming .
ENERGY STORAGE MATERIALS, 2020, 27 :205-211
[8]   Stabilizing zinc anode via a chelation and desolvation electrolyte additive [J].
Cao, Jin ;
Zhang, Dongdong ;
Chanajaree, Rungroj ;
Yue, Yilei ;
Zeng, Zhiyuan ;
Zhang, Xinyu ;
Qin, Jiaqian .
ADVANCED POWDER MATERIALS, 2022, 1 (01)
[9]   Fluorinated interphase enables reversible aqueous zinc battery chemistries [J].
Cao, Longsheng ;
Li, Dan ;
Pollard, Travis ;
Deng, Tao ;
Zhang, Bao ;
Yang, Chongyin ;
Chen, Long ;
Vatamanu, Jenel ;
Hu, Enyuan ;
Hourwitz, Matt J. ;
Ma, Lin ;
Ding, Michael ;
Li, Qin ;
Hou, Singyuk ;
Gaskell, Karen ;
Fourkas, John T. ;
Yang, Xiao-Qing ;
Xu, Kang ;
Borodin, Oleg ;
Wang, Chunsheng .
NATURE NANOTECHNOLOGY, 2021, 16 (08) :902-+
[10]   Fast-Charging and Ultrahigh-Capacity Zinc Metal Anode for High-Performance Aqueous Zinc-Ion Batteries [J].
Cao, Penghui ;
Zhou, Xiangyang ;
Wei, Anran ;
Meng, Qi ;
Ye, Han ;
Liu, Weiping ;
Tang, Jingjing ;
Yang, Juan .
ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (20)
12345678910