Reaction of (Z,E)-2-(Alkylsulfanyl)alk-2-en-4-ynals with N,N- and N,O-Binucleophiles

被引:1
作者
Fedoseeva, V. G. [1 ]
Verochkina, E. A. [1 ]
Larina, L. I. [1 ]
Vchislo, N. V. [1 ]
机构
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
基金
俄罗斯基础研究基金会;
关键词
enynals; alpha; beta-unsaturated aldehydes; condensation reaction; imidazolidine; oxazolidine;
D O I
10.1134/S1070428023020161
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The condensation of 2-alkylsulfanyl-substituted 2-en-4-ynals with N,N- and N,O-binucleophiles gives the corresponding 1,3-perhydrodiazines, 1,3-imidazolidines, and 1,3-oxazolidines with the original combination of substituents.
引用
收藏
页码:332 / 336
页数:5
相关论文
共 15 条
  • [1] Synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol
    Buser, D
    Pauling, H
    Thum, A
    Bonrath, W
    [J]. MOLECULES, 2002, 7 (03) : 341 - 352
  • [2] Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization
    Fedoseeva, Victoria G.
    Verochkina, Ekaterina A.
    Larina, Ludmila, I
    Kondrashov, Evgeniy, V
    Rozentsveig, Igor B.
    Vchislo, Nadezhda V.
    [J]. MENDELEEV COMMUNICATIONS, 2021, 31 (06) : 856 - 858
  • [3] Conjugated 2,4,1-and 1,4,3-enynones as polycentricelectrophiles in synthesis of heterocyclic compounds
    Golovanov, Alexander A.
    Gusev, Dmitry M.
    Odin, Ivan S.
    Zlotskii, Simon S.
    [J]. CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2019, 55 (4-5) : 333 - 348
  • [4] Conjugated enynones: preparation, properties and applications in organic synthesis
    Golovanov, Alexander A.
    Odin, Ivan S.
    Zlotskii, Simon S.
    [J]. RUSSIAN CHEMICAL REVIEWS, 2019, 88 (03) : 280 - 318
  • [5] HOFFMAN RV, 1974, J ORG CHEM, V39, P2939
  • [6] RING-OPENING REACTIONS OF FURFURYLIDENES
    HOFFMAN, RV
    SHECHTER, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (22) : 5940 - &
  • [7] CARBENIC, CATIONIC, METAL-ION CATALYZED, AND PHOTOLYTIC DECOMPOSITIONS OF ETHYL (2-FURYL)DIAZOACETATE
    HOFFMAN, RV
    SHECHTER, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (25) : 7934 - 7940
  • [8] CHEMISTRY OF (2-FURYL-METHYLENE AND 3-FURYL)METHYLENE AND (2-THIENYL AND 3-THIENYL)METHYLENES-1A
    HOFFMAN, RV
    ORPHANIDES, GG
    SHECHTER, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (25) : 7927 - 7933
  • [9] Synthesis, molecular properties, toxicity and biological evaluation of some new substituted imidazolidine derivatives in search of potent anti-inflammatory agents
    Husain, Asif
    Ahmad, Aftab
    Khan, Shah Alam
    Asif, Mohd
    Bhutani, Rubina
    Al-Abbasi, Fahad A.
    [J]. SAUDI PHARMACEUTICAL JOURNAL, 2016, 24 (01) : 104 - 114
  • [10] Stereoselective Synthesis of Multisubstituted Cyclohexanes by Reaction of Conjugated Enynones with Malononitrile in the Presence of LDA
    Igushkina, Anastasiya V.
    Golovanov, Alexander A.
    Boyarskaya, Irina A.
    Kolesnikov, Ilya E.
    Vasilyev, Aleksander V.
    [J]. MOLECULES, 2020, 25 (24):