Broadband dielectric relaxation investigations of polyvinyl chloride-fGO nanocomposite films

被引:4
作者
Alrowaili, Z. A. [1 ]
Ahmed, R. M. [2 ]
Saleh, Ahmed [3 ]
Mebed, Abdelazim M. [1 ]
Taha, T. A. [1 ]
机构
[1] Jouf Univ, Coll Sci, Phys Dept, POB 2014, Sakaka, Saudi Arabia
[2] Zagazig Univ, Fac Sci, Phys Dept, Zagazig 44519, Egypt
[3] Sci & Technol Ctr Excellence STCE, Cairo, Egypt
关键词
Polymer nanocomposites; Dielectric constant; Activation energy; AC conductivity; ENERGY-STORAGE; ELECTRICAL-PROPERTIES; POLYMER; CONDUCTIVITY; COMPOSITES; MODULUS;
D O I
10.1007/s00289-022-04217-y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The use of polymer nanocomposites in different electrical applications stimulated the study of the dielectric properties for PVC-fGO films at different temperatures. The high values of epsilon MODIFIER LETTER PRIME of the different nanocomposites, at low frequencies, are due to the space charge effect induced by electrode polarization. The values of maximum barrier height (W-M) decrease by increasing the applied temperature whereas they are independent of the content of fGo in the different nanocomposites. The values of real dielectric modulus (MMODIFIER LETTER PRIME) decreased by increasing fGO content (except for 0.5 wt% of fGO nanofiller). A shift in the position M" peak to higher frequencies by increasing the temperature was observed. The values of sigma(AC) increase by increasing the fGO content up to 0.3 wt% while decreasing at 0.5 and 1.0 wt% of fGO. Increasing the fGO content in the nanocomposites causes the values of DC activation energy (E-DC) to increase up to 0.3 wt% of fGO then they decreased, due to the space charge effect.
引用
收藏
页码:3293 / 3308
页数:16
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