Preparation of KH550-grafted-nanosilica microspheres to improve the mechanical, thermal and wear resistance properties of fluoroelastomer

被引:0
作者
Shen, Ping [1 ]
Bao, Yong [1 ]
Zhang, Yiwen [1 ]
Wu, Yadong [1 ]
Li, Jun [1 ]
Wang, Shun [1 ,2 ]
Zhu, Yong [3 ]
Gao, Junchang [1 ,4 ]
Jin, Huile [1 ,2 ,5 ]
机构
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou Key Lab Adv Energy Storage & Convers, Zhejiang Prov Key Lab Leather Engn, Wenzhou, Peoples R China
[2] Wenzhou Univ, Inst New Mat & Ind Technol, Zhejiang Engn Res Ctr Electrochem Energy Mat & dev, Wenzhou, Peoples R China
[3] Ouhong Sealing, Wenzhou, Peoples R China
[4] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou Key Lab Adv Energy Storage & Convers, Zhejiang Prov Key Lab Leather Engn, Chashan Univ Town, Wenzhou 325035, Peoples R China
[5] Wenzhou Univ, Inst New Mat & Ind Technol, Zhejiang Engn Res Ctr Electrochem Energy Mat & Dev, Wenzhou 325025, Peoples R China
基金
中国国家自然科学基金;
关键词
Silica microspheres; nanocomposites; chemical modification; mechanical properties; thermal properties; wear properties; SILICA; PARTICLE; LIQUID; SEALS;
D O I
10.1177/08927057241239004
中图分类号
TB33 [复合材料];
学科分类号
摘要
We presents an innovative approach to addressing the mechanical properties limitations of fluororubber (FKM) in the industrial field. A novel functionalized nano-silica spheres (SiO2), grafted with amino groups, were constructed by utilizing chemical grafting. The surface modification of the nanosilica microspheres enables the formation of C=N bonds between the amino-functionalized nanosilica microspheres and FKM promoting high dispersion and strong interfacial bonding of SiO2, resulting in an exceptional mechanical enhancement function for FKM composite. Compared to original FKM, the FKM/SM-A-10 composite demonstrates remarkable improvements in both tensile strength and hardness by 242% and 49%, respectively. Additionally, there is a notable 40% enhancement in thermal conductivity of the FKM/SM-A-10 composite. This straightforward and efficient manufacturing approach for achieving high-performance FKM proves to be a valuable and practical foundation for industrial design.
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页码:3652 / 3668
页数:17
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