Application of carbon materials in catalytic systems for the hydrogenation-dehydrogenation of liquid organic hydrogen carriers

被引：1
|
作者：
Kalenchuk, A. N. [1 ,2 ]
Bogdan, V. I. [1 ,2 ]
Dunaev, S. F. [1 ]
Kustov, L. M. [1 ,2 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, 1-3 Leninskie Gory, Moscow 119991, Russia
[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Leninsky Prosp 47, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
carbon catalyst carriers; hydrogenation; dehydrogenation; hydrogen storage; POLYCYCLIC AROMATIC-HYDROCARBONS; METHANE DECOMPOSITION; ACTIVATED CARBON; GRAPHENE OXIDE; BICYCLOHEXYL DEHYDROGENATION; PD NANOPARTICLES; HYDROTHERMAL SYNTHESIS; SURFACE-CHEMISTRY; STORAGE-SYSTEMS; PT/C CATALYST;
D O I：
10.1007/s11172-024-4118-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Carbon materials with different textural characteristics (active carbon, carbon nanotubes, and Sibunite) for the purposes of hydrogen generation and storage and its evolution in processes using liquid organic hydrogen carriers are compared. A combination of structural and physicochemical characteristics (surface functionalization, controlled metal-carbon interaction, and relative chemical inertness) provides advantages of the modern carbon materials over oxides as catalyst carriers, since they allow the accumulation (hydrogenation) and evolution (dehydrogenation) of hydrogen to occur without cracking product formation. The prospects of the Sibunite-based Pt catalysts in these reactions are shown.
引用
收藏
页码：1 / 13
页数：13
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