Solid-state polymer electrolytes in lithium batteries: latest progress and perspective

被引：20

作者：

Mu, Jingbo ^{[1
]}

Liao, Shimin ^{[1
]}

Shi, Linlin ^{[2
]}

Su, Bihai ^{[2
]}

Xu, Feng ^{[2
]}

Guo, Zengcai ^{[1
]}

Li, Hailing ^{[1
]}

Wei, Fangfang ^{[1
]}

机构：

[1] Hebei Univ Engn, Coll Mat Sci & Engn, Key Lab New Energy Dev & Energy Storage Technol Ha, Handan 056038, Peoples R China

[2] Hebei Gellec New Energy Sci & Technol Co Ltd, Handan 057150, Peoples R China

来源：

POLYMER CHEMISTRY | 2024年 / 15卷 / 06期

关键词：

IN-SALT ELECTROLYTE; IONIC-CONDUCTIVITY; POLY(ETHYLENE OXIDE); METAL BATTERIES; COMPOSITE; PERFORMANCE; STABILITY; TRANSPORT; INTERPHASE; CARBONATE;

D O I：

10.1039/d3py01311a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The increasing demands for battery performance in the new era of energy necessitate urgent research and development of an energy storage battery that offers high stability and a long service life. Among the various types of batteries available, the all-solid lithium battery emerges as the preferred choice because of its exceptional safety, stability, and sustainability features. The solid electrolyte plays a crucial role in facilitating efficient energy transmission within the structure of the lithium battery. Solid electrolytes based on polymer chemistry can be classified into different categories, such as ether-based, ester-based, nitrile-based, and polyvinylidene fluoride materials. This discussion also covers topics such as ion transport mechanisms, levels of ionic conductivity, techniques for modification, and analysis of cyclic stability specifically for lithium-ion batteries utilizing solid electrolytes. Finally, an outlook on the future research direction of solid-state polymer electrolytes is suggested for commercially large-scale production and application. This review provides a comprehensive overview of solid-state polymer electrolytes performance characteristics of various chemical structures such as ethers, esters, nitrile and vinylidene fluoride.

引用

页码：473 / 499

页数：27

共 175 条

[11] Rearrangement of Ion Transport Path on Nano-Cross-linker for All-Solid-State Electrolyte with High Room Temperature Ionic Conductivity [J].

Cai, Xiaomin ;

Ding, Jianlong ;

Chi, Ziyun ;

Wang, Wenqiang ;

Wang, Dongya ;

Wang, Gengchao .

ACS NANO, 2021, 15 (12) :20489-20503

[12] Interfacial Issues and Modification of Solid Electrolyte Interphase for Li Metal Anode in Liquid and Solid Electrolytes [J].

Chae, Oh B. ;

Lucht, Brett L. .

ADVANCED ENERGY MATERIALS, 2023, 13 (14)

[13] Regulation of Interphase Layer by Flexible Quasi-Solid Block Polymer Electrolyte to Achieve Highly Stable Lithium Metal Batteries [J].

Chai, Simin ;

Chang, Zhi ;

Zhong, Yue ;

He, Qiong ;

Wang, Yijiang ;

Wan, Yuanlang ;

Feng, MingYang ;

Hu, Yingzhu ;

Li, WeiHang ;

Wei, Weifeng ;

Pan, Anqiang .

ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (27)

[14] Stable Seamless Interfaces and Rapid Ionic Conductivity of Ca-CeO2/LiTFSI/PEO Composite Electrolyte for High-Rate and High-Voltage All-Solid-State Battery [J].

Chen, Hao ;

Adekoya, David ;

Hencz, Luke ;

Ma, Jun ;

Chen, Su ;

Yan, Cheng ;

Zhao, Huijun ;

Cui, Guanglei ;

Zhang, Shanqing .

ADVANCED ENERGY MATERIALS, 2020, 10 (21)

[15] A novel organic/inorganic composite solid electrolyte with functionalized layers for improved room-temperature rate performance of solid-state lithium battery [J].

Chen, Hao ;

Jing, Mao-xiang ;

Han, Chong ;

Yang, Hua ;

Hua, Song ;

Chen, Fei ;

Chen, Li-Li ;

Zhou, Zu-xu ;

Ju, Bo-wei ;

Tu, Fei-yue ;

Shen, Xiang-qian ;

Qin, Shi-biao .

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2019, 43 (11) :5912-5921

[16] PEO-based solid-state electrolyte modified by cationic covalent organic frameworks enabling high-performance all-solid-state Li metal and graphite anode batteries [J].

Chen, Jing ;

Han, Sheng .

CHEMICAL ENGINEERING JOURNAL, 2023, 470

[17] Research progress and application prospect of solid-state electrolytes in commercial lithium-ion power batteries [J].

Chen, Jing ;

Wu, Jiawei ;

Wang, Xiaodong ;

Zhou, An'an ;

Yang, Zhenglong .

ENERGY STORAGE MATERIALS, 2021, 35 (35) :70-87

[18] Zeolitic imidazolate framework-67 based separator for enhanced high thermal stability of lithium ion battery [J].

Chen, Pan ;

Shen, Jianxing ;

Wang, Tailin ;

Dai, Meng ;

Si, Conghui ;

Xie, Jixun ;

Li, Min ;

Cong, Xiaotong ;

Sun, Xiao .

JOURNAL OF POWER SOURCES, 2018, 400 :325-332

[19] Poly(Ether-Ester)-Based Solid Polymer Electrolytes with High Li-Ion Transference Number for High Voltage All-Solid-State Lithium Metal Batteries [J].

Chen, Yang ;

Zhang, Yin ;

Niu, Jianda ;

Xu, Hongli ;

Dong, Zhixian ;

Xu, Jinbao ;

Lei, Caihong .

ACS APPLIED ENERGY MATERIALS, 2023, 6 (05) :3113-3125

[20] Anisotropic Ion Transport in a Poly(ethylene oxide)-LiClO4 Solid State Electrolyte Templated by Graphene Oxide [J].

Cheng, Shan ;

Smith, Derrick M. ;

Li, Christopher Y. .

MACROMOLECULES, 2015, 48 (13) :4503-4510

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