Role of Transition Metals in Pt Alloy Catalysts for the Oxygen Reduction Reaction

被引：68

作者：

Lim, Chaewon ^{[1
,2
]}

Fairhurst, Alasdair R. ^{[1
,2
]}

Ransom, Benjamin J. ^{[1
,2
]}

Haering, Dominik ^{[1
,2
]}

Stamenkovic, Vojislav R. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Irvine, Dept Chem & Biomol Engn, Irvine, CA 92697 USA

[2] Univ Calif Irvine, HORIBA Inst Mobil & Connect, Irvine, CA 92697 USA

[3] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ACS CATALYSIS | 2023年 / 13卷 / 22期

关键词：

electrocatalysis; oxygen reduction reaction; platinum alloy; transition metal; ligand effect; strain effect; surface science; spectroscopy; SINGLE-CRYSTAL SURFACES; PLATINUM DISSOLUTION; ELECTRONIC-STRUCTURE; BIMETALLIC SURFACES; ATOMIC-STRUCTURE; CO OXIDATION; THIN-FILMS; PT-SKIN; CELL; ELECTROCATALYSIS;

D O I：

10.1021/acscatal.3c03321

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In pursuit of higher activity and stability of electrocatalysts toward the oxygen reduction reaction, it has become standard practice to alloy platinum in various structural configurations. Transition metals have been extensively studied for their ability to tune catalyst functionality through strain, ligand, and ensemble effects. The origin of these effects and potential for synergistic application in practical materials have been the subject of many theoretical and experimental analyses in recent years. Here, a comprehensive overview of these phenomena is provided regarding the impact on reaction mechanisms and kinetics through combined experimental and theoretical approaches. Experimental approaches to electrocatalysis are discussed.

引用

页码：14874 / 14893

页数：20

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