Role of Transition Metals in Pt Alloy Catalysts for the Oxygen Reduction Reaction

被引:46
作者
Lim, Chaewon [1 ,2 ]
Fairhurst, Alasdair R. [1 ,2 ]
Ransom, Benjamin J. [1 ,2 ]
Haering, Dominik [1 ,2 ]
Stamenkovic, Vojislav R. [1 ,2 ,3 ]
机构
[1] Univ Calif Irvine, Dept Chem & Biomol Engn, Irvine, CA 92697 USA
[2] Univ Calif Irvine, HORIBA Inst Mobil & Connect, Irvine, CA 92697 USA
[3] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
关键词
electrocatalysis; oxygen reduction reaction; platinum alloy; transition metal; ligand effect; strain effect; surface science; spectroscopy; SINGLE-CRYSTAL SURFACES; PLATINUM DISSOLUTION; ELECTRONIC-STRUCTURE; BIMETALLIC SURFACES; ATOMIC-STRUCTURE; CO OXIDATION; THIN-FILMS; PT-SKIN; CELL; ELECTROCATALYSIS;
D O I
10.1021/acscatal.3c03321
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In pursuit of higher activity and stability of electrocatalysts toward the oxygen reduction reaction, it has become standard practice to alloy platinum in various structural configurations. Transition metals have been extensively studied for their ability to tune catalyst functionality through strain, ligand, and ensemble effects. The origin of these effects and potential for synergistic application in practical materials have been the subject of many theoretical and experimental analyses in recent years. Here, a comprehensive overview of these phenomena is provided regarding the impact on reaction mechanisms and kinetics through combined experimental and theoretical approaches. Experimental approaches to electrocatalysis are discussed.
引用
收藏
页码:14874 / 14893
页数:20
相关论文
共 133 条
[1]   Scaling properties of adsorption energies for hydrogen-containing molecules on transition-metal surfaces [J].
Abild-Pedersen, F. ;
Greeley, J. ;
Studt, F. ;
Rossmeisl, J. ;
Munter, T. R. ;
Moses, P. G. ;
Skulason, E. ;
Bligaard, T. ;
Norskov, J. K. .
PHYSICAL REVIEW LETTERS, 2007, 99 (01)
[2]   Potential Dependence of Pt and Co Dissolution from Platinum-Cobalt Alloy PEFC Catalysts Using Time-Resolved Measurements [J].
Ahluwalia, Rajesh K. ;
Papadias, Dionissios D. ;
Kariuki, Nancy N. ;
Peng, Jui-Kun ;
Wang, Xiaoping ;
Tsai, Yifen ;
Graczyk, Donald G. ;
Myers, Deborah J. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (06) :F3024-F3035
[3]   Moving forward with fuel cells [J].
不详 .
NATURE ENERGY, 2021, 6 (05) :451-451
[4]   Oxygen Reduction Reaction Activity for Strain-Controlled Pt-Based Model Alloy Catalysts: Surface Strains and Direct Electronic Effects Induced by Alloying Elements [J].
Asano, Masato ;
Kawamura, Ryutaro ;
Sasakawa, Ren ;
Todoroki, Naoto ;
Wadayama, Toshimasa .
ACS CATALYSIS, 2016, 6 (08) :5285-5289
[5]   Current Status and Future Development of Catalyst Materials and Catalyst Layers for Proton Exchange Membrane Fuel Cells: An Industrial Perspective [J].
Banham, Dustin ;
Ye, Siyu .
ACS ENERGY LETTERS, 2017, 2 (03) :629-638
[6]   Control of Architecture in Rhombic Dodecahedral Pt-Ni Nanoframe Electrocatalysts [J].
Becknell, Nigel ;
Son, Yoonkook ;
Kim, Dohyung ;
Li, Dongguo ;
Yu, Yi ;
Niu, Zhiqiang ;
Lei, Teng ;
Sneed, Brian T. ;
More, Karren L. ;
Markovic, Nenad M. ;
Stamenkovic, Vojislav R. ;
Yang, Peidong .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (34) :11678-11681
[7]   Real-time imaging of activation and degradation of carbon supported octahedral Pt-Ni alloy fuel cell catalysts at the nanoscale using in situ electrochemical liquid cell STEM [J].
Beermann, Vera ;
Holtz, Megan E. ;
Padgett, Elliot ;
de Araujo, Jorge Ferreira ;
Muller, David A. ;
Strasser, Peter .
ENERGY & ENVIRONMENTAL SCIENCE, 2019, 12 (08) :2476-2485
[8]   CO oxidation on Pt(111) promoted by coadsorbed H2O [J].
Bergeld, J ;
Kasemo, B ;
Chakarov, DV .
SURFACE SCIENCE, 2001, 495 (03) :L815-L820
[9]   Ligand effects in heterogeneous catalysis and electrochemistry [J].
Bligaard, T. ;
Norskov, J. K. .
ELECTROCHIMICA ACTA, 2007, 52 (18) :5512-5516
[10]   The Bronsted-Evans-Polanyi relation and the volcano curve in heterogeneous catalysis [J].
Bligaard, T ;
Norskov, JK ;
Dahl, S ;
Matthiesen, J ;
Christensen, CH ;
Sehested, J .
JOURNAL OF CATALYSIS, 2004, 224 (01) :206-217