PEO coating on Mg-Ag alloy: The incorporation and release of Ag species

被引:30
|
作者
Zhang, Xinxin [1 ,2 ]
Zhang, Yupeng [1 ,2 ]
Lv, You [1 ,2 ]
Dong, Zehua [1 ]
Yang, Lei [3 ]
Zhang, Erlin [3 ]
Hashimoto, Teruo [4 ]
Zhou, Xiaorong [4 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage,Minist E, Wuhan 430074, Peoples R China
[2] Huazhong Univ Sci & Technol, Hubei Engn Res Ctr Biomat & Med Protect Mat, Wuhan 430074, Peoples R China
[3] Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat, Educ Minist China, Shenyang 110819, Peoples R China
[4] Univ Manchester, Corros & Protect Ctr, Dept Mat, Manchester M13 9PL, England
基金
中国国家自然科学基金;
关键词
Mg-Ag alloy; Plasma electrolytic oxidation; Ag distribution; Ag release; Corrosion resistance; BIODEGRADABLE MAGNESIUM ALLOYS; ANODIC FILM FORMATION; IN-VITRO; CORROSION-RESISTANCE; STAINLESS-STEEL; TIO2; COATINGS; ANTIBACTERIAL; CU; OXIDATION; COPPER;
D O I
10.1016/j.jma.2021.12.006
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
In the present study, the distribution of Ag in the coating formed on Mg-Ag alloy by plasma electrolytic oxidation (PEO) and its ionic release kinetics when exposed to a 0.9 wt.% NaCl solution at 37 & DEG;C have been investigated. Both metallic Ag and Ag oxide particles with & SIM;5 to & SIM;40 nm in diameters were observed in the PEO coating. Further, an Ag-enriched layer of & SIM;20 nm in thickness at the substrate/coating interface was also observed. The PEO coating on the Mg-Ag alloy not only increases its corrosion resistance with the corrosion current density decreasing by up to 3 orders of magnitude from 8.04 x 10 -3 to 4.03 x 10 -6 A/cm 2 , but also controls the release of Ag + to the level that is sufficient for anti-infective efficacy without causing cytotoxicity to mammal cells. & COPY; 2022 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University
引用
收藏
页码:2182 / 2195
页数:14
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