Harvesting 88Zr from heavy-ion beam irradiated tungsten at the National Superconducting Cyclotron Laboratory

被引:0
作者
Satija, Samridhi [1 ,2 ]
Domnanich, Katharina A. [1 ,2 ]
Bence, Jake A. [3 ,4 ]
Vyas, Chirag K. [2 ]
Abel, E. Paige [1 ,2 ]
Kleinfeldt, Chloe [1 ,2 ]
Essenmacher, Scott [1 ,2 ]
Kalman, Morgan [2 ]
Walker, Wesley [2 ]
Despotopulos, John D. [5 ]
Scielzo, Nicholas D. [5 ]
Shusterman, Jennifer A. [3 ,4 ,5 ]
Severin, Gregory W. [1 ,2 ,6 ]
机构
[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
[2] Facil Rare Isotope Beams, E Lansing, MI 48824 USA
[3] City Univ New York, Hunter Coll, New York, NY 10065 USA
[4] City Univ New York, Grad Ctr, New York, NY 10016 USA
[5] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA
[6] Michigan State Univ, Facil Rare Isotope Beams, 640 S Shaw Ln, E Lansing, MI 48824 USA
基金
美国国家科学基金会;
关键词
Radiochemical separation; Isotope harvesting; Tungsten; 88Zr; NUCLEAR-DATA SHEETS; WATER TARGET; SEPARATION; MOLYBDENUM; EXCHANGE; DISSOLUTION; ZR-89; ACID;
D O I
10.1016/j.apradiso.2023.110831
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Tungsten is a commonly used material at many heavy-ion beam facilities, and it often becomes activated due to interactions with a beam. Many of the activation products are useful in basic and applied sciences if they can be recovered efficiently. In order to develop the radiochemistry for harvesting group (IV) elements from irradiated tungsten, a heavy-ion beam containing 88Zr was embedded into a stack of tungsten foils at the National Superconducting Cyclotron Laboratory and a separation methodology was devised to recover the 88Zr. The foils were dissolved in 30% hydrogen peroxide, and the 88Zr was chemically purified from the tungsten matrix and from other co-implanted radionuclides (such as 85Sr and 88Y) using strong cation-exchange (AG MP-50) chromatographic resin in sulfuric acid media. The procedure provided 88Zr in approximately 60 mL 0.5 M sulfuric acid with no detectable radio-impurities. The overall recovery yield for 88Zr was (92.3 +/- 1.2)%. This proof-ofconcept experiment has facilitated the development of methodologies to harvest from tungsten and tungstenalloy parts that are regularly irradiated at heavy-ion beam facilities.
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页数:8
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