Propane metathesis and hydrogenolysis over titanium hydride catalysts

被引：1
|
作者：
Huang, Mengwen [1 ]
Tomimuro, Yosuke [1 ]
Miyazaki, Shinta [1 ]
Mine, Shinya [1 ]
Toyao, Takashi [1 ]
Hinuma, Yoyo [2 ]
Kanda, Yasuharu [3 ]
Kitano, Masaaki [4 ,5 ]
Shimizu, Ken-ichi [1 ]
Maeno, Zen [6 ]
机构：
[1] Hokkaido Univ, Inst Catalysis, N-21,W-10, Sapporo, Hokkaido 0010021, Japan
[2] Natl Inst Adv Ind Sci & Technol, Environm & Energy Dept, 1-8-31 Midorigaoka, Ikeda, Osaka 5638577, Japan
[3] Muroran Inst Technol, Grad Sch Engn, Coll Informat & Syst, Chem & Biol Engn Res Unit, 27-1 Mizumoto, Muroran, Hokkaido 0508585, Japan
[4] MDX Res Ctr Element Strategy Int Res Frontiers In, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[5] Tohoku Univ, Adv Inst Mat Res WPI AIMR, Sendai, Miyagi 9808577, Japan
[6] Kogakuin Univ, Sch Adv Engn, 2665-1 Nakano Cho, Hachioji, Tokyo 1920015, Japan
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2023年 / 13卷 / 21期
基金：
日本学术振兴会;
关键词：
SUPPORTED TANTALUM HYDRIDE; ALKANE METATHESIS; CALCIUM HYDRIDES; SILICA; SURFACE; HOMOLOGATION; BARIUM;
D O I：
10.1039/d3cy01187a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Propane metathesis reactions over group 2-5 metal hydrides were investigated. Among the tested metal hydrides, TiH2 exhibited the highest butane yield as a metathesis reaction product. Fully-hydrogenated TiH2 is much more active than dehydrogenated TiH and Ti metal. Surface low-valent Ti species over TiH2 is involved in the propane metathesis reaction. This study is the first example of carbon-carbon bond cleavage and catalytic formation over bulk metal hydrides. Propane metathesis reactions over group 2-5 metal hydrides were investigated where TiH2 exhibited the highest butane formation amount. This study is the first example of carbon-carbon bond cleavage and formation over bulk metal hydrides.
引用
收藏
页码：6247 / 6253
页数：7
相关论文
共 50 条
  • [1] Hydrogenolysis of propane and n-butane over rhodium catalysts
    Bond, GC
    Calhoun, J
    Hooper, AD
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (24): : 5117 - 5128
  • [2] ETHANE AND PROPANE HYDROGENOLYSIS ON RU CATALYSTS
    GALVAGNO, S
    SCHWANK, J
    GUBITOSA, G
    TAUSZIK, GR
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1982, 78 : 2509 - 2520
  • [3] PROPANE HYDROGENOLYSIS OVER SUPPORTED NICKEL-CATALYSTS - STRUCTURAL AND SUPPORT EFFECTS
    BURKE, PA
    KO, EI
    JOURNAL OF CATALYSIS, 1989, 116 (01) : 230 - 239
  • [4] Demystifying group-4 polyolefin hydrogenolysis catalysis: Gaseous propane hydrogenolysis mechanism over the same catalysts
    Mason, Alexander H.
    Motta, Alessandro
    Kratish, Yosi
    Marks, Tobin J.
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2024, 121 (30)
  • [5] ACTIVITY AND PROPERTIES OF NICKEL CATALYSTS IN HYDROGENOLYSIS OF PROPANE
    SHEPHARD, FE
    JOURNAL OF CATALYSIS, 1969, 14 (02) : 148 - &
  • [6] Kinetic analysis of the hydrogenolysis of propane on ruthenium catalysts
    Geoffrey C. Bond
    Andrew D. Hooper
    Reaction Kinetics and Catalysis Letters, 1999, 68 : 5 - 14
  • [7] Kinetic analysis of the hydrogenolysis of propane on ruthenium catalysts
    Bond, GC
    Hooper, AD
    REACTION KINETICS AND CATALYSIS LETTERS, 1999, 68 (01): : 5 - 14
  • [8] MECHANISM AND STRUCTURE SENSITIVITY OF PROPANE HYDROGENOLYSIS OVER NI-SIO2 CATALYSTS
    GUILLEUX, MF
    DALMON, JA
    MARTIN, GA
    JOURNAL OF CATALYSIS, 1980, 62 (02) : 235 - 242
  • [9] RETRACTED: Hydrogenolysis of Polyethylene and Polypropylene into Propane over Cobalt-Based Catalysts (Retracted Article)
    Zichittella, Guido
    Ebrahim, Amani M.
    Zhu, Jie
    Brenner, Anna E.
    Drake, Griffin
    Beckham, Gregg T.
    Bare, Simon R.
    Rorrer, Julie E.
    Roman-Leshkov, Yuriy
    JACS AU, 2022, 2 (10): : 2259 - 2268
  • [10] HYDROGENOLYSIS OF PROPANE ON SUPPORTED CATALYSTS OF NICKEL, COBALT, IRON, AND RUTHENIUM
    MACHIELS, CJ
    ANDERSON, RB
    JOURNAL OF CATALYSIS, 1979, 58 (02) : 253 - 259
12345