NiCo layered double hydroxide nanocages for high-performance asymmetric supercapacitors

被引：46

作者：

Jiang, Hualin ^{[1
,2
]}

Ke, Qi ^{[1
,2
]}

Qiu, Xianhua ^{[1
,2
]}

Chen, Jiezeng ^{[1
,2
]}

Chen, Pinghua ^{[1
,2
]}

Wang, Shuai ^{[1
,2
]}

Luo, Xubiao ^{[1
,2
,3
]}

Rao, Bingying ^{[2
]}

机构：

[1] Key Lab Jiangxi Prov Persistent Pollutants Control, Nanchang 330063, Peoples R China

[2] Nanchang Hangkong Univ, Dept Environm & Chem Engn, Nanchang 330063, Peoples R China

[3] Jinggangshan Univ, Sch Life Sci, Jian 343009, Peoples R China

来源：

INORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 07期

基金：

中国国家自然科学基金;

关键词：

NANOSHEETS; LDH; ELECTRODES; DESIGN; SHEETS;

D O I：

10.1039/d2qi02763a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, well-designed NiCo layered double hydroxide (NiCo-LDH) nanocages are prepared by a simple Cu2O template etching method. Due to their unique hollow structures and synergistic effects, NiCo-LDH-1 (molar ratio of Ni and Co is 1 : 1) nanocages exhibit superior capacitance (1671 F g(-1)@1 A g(-1)) in a three-electrode system. In addition, a supercapacitor device is prepared with NiCo-LDH-1 nanocages as the cathode and active carbon (AC) as the anode which shows a maximum energy density of 59.0 W h kg(-1)@935.7 W kg(-1) power density and displays high cycling stability with a capacitance retention rate of 87.1% after 10 000 cycles at 10 A g(-1). A light emitting diode was powered by the assembled supercapacitor and remained illuminated for similar to 12 min. In order to understand the charge storage mechanism of supercapacitors during the electrochemical charge/discharge process, the structure of NiCo-LDH-1 was studied in detail by in situ X-Ray Diffraction (XRD).

引用

页码：2154 / 2164

页数：11

共 64 条

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