Seminormal-BrCH2CH2OH-mediated electrochemical epoxidation of unactivated olefins

被引：24
作者：
He, Hong [1 ,2 ,3 ]
Lv, Yanxia [1 ,2 ,3 ]
Hu, Jing [1 ,2 ]
Hou, Zhong-Wei [1 ,2 ]
Wang, Lei [1 ,2 ,3 ,4 ,5 ]
机构：
[1] Taizhou Univ, Adv Res Inst, Jiaojiang 318000, Zhejiang, Peoples R China
[2] Taizhou Univ, Sch Pharmaceut Sci, Jiaojiang 318000, Zhejiang, Peoples R China
[3] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[4] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China
[5] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
GREEN CHEMISTRY | 2024年 / 26卷 / 04期
基金：
中国国家自然科学基金;
关键词：
C-H; WATER; HALOGENATION; EPOXIDES; ETHYLENE; OXIDES;
D O I：
10.1039/d3gc04061e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An electrochemical epoxidation of unactivated olefins using water as the source of oxygen atoms has been developed. The epoxidation reaction employs seminormal-BrCH2CH2OH as the mediator, which shows good functional group compatibility, and can easily be performed on the gram scale. A wide range of unactivated olefins could be tolerated to give the functionalized epoxides with satisfactory results at room temperature.
引用
收藏
页码：2157 / 2161
页数：5
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