CO2 sequestration and CaCO3 recovery with steel slag by a novel two-step leaching and carbonation method

被引:35
作者
Cheng, Can [1 ]
Huang, Wenjun [1 ]
Xu, Haomiao [1 ]
Liu, Zhisong [1 ]
Li, Xianwei [2 ]
Shi, Hongzhi [2 ]
Yu, Yongmei [2 ]
Qu, Zan [1 ]
Yan, Naiqiang [1 ,3 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China
[2] Baoshan Iron & Steel Co Ltd, Shanghai 201999, Peoples R China
[3] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
基金
中国国家自然科学基金;
关键词
Steel slag; Leaching; Carbonation; CO2; sequestration; Recycling; OXYGEN FURNACE SLAG; KINETICS; DIOXIDE; CAPTURE; IRON; SERPENTINITE; DISSOLUTION; FIXATION; ACID; FE;
D O I
10.1016/j.scitotenv.2023.164203
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The steel smelting process produces extensive CO2 and Ca-containing steel slag (SS). Meanwhile, the low value utili-zation of steel slag results in the loss of Ca resources. CO2 sequestration utilizing SS can reduce carbon emissions while achieving Ca circulation. However, conventional SS carbon sequestration methods suffer from slow reaction rates, finite Ca usage efficiency, and difficulty separating the CaCO3 product from SS. Herein, an innovative two-step leaching (TSL) and carbonation method was presented based on the variations in leaching efficiency of activated Ca under different conditions, aiming at efficient leaching, carbon sequestration, and high-value reuse of SS. This method employed two NH4Cl solutions in sequence for two leaching operations on SS, allowing the Ca leaching rate to be effectively increased. According to the findings, TSL could increase the activated Ca leaching rate by 26.9 % and achieve 223.15 kg CO2/t SS sequestration compared to the conventional one-step leaching (CSL) method. If part of the CaCO3 is recovered as a slagging agent, about 34.1 % of the exogenous Ca introduction could be saved. In addition, the CO2 sequestration of TSL did not significantly decrease after 8 cycles. This work proposes a strategy that has the potential for recycling SS and reducing carbon emissions.
引用
收藏
页数:12
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