(η5-Pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride

被引：0
作者：
Bandaru, Sravan K. [1 ]
Marr, Andrew C. [2 ]
Saunders, Graham C. [1 ]
机构：
[1] Univ Waikato, Sch Sci, Private Bag 3105, Hamilton 3105, New Zealand
[2] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, North Ireland
来源：
MOLBANK | 2023年 / 2023卷 / 02期
关键词：
N-heterocycle carbene; iridium; X-ray structure; COMPLEXES; FLUORINE;
D O I：
10.3390/M1641
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this paper, we report (& eta;(5)-pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride, 2, synthesized using a silver transfer agent generated from 1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide. Compound 2 was characterized using H-1 and F-19 NMR spectroscopy and mass spectrometry, and its structure was determined in a single-crystal X-ray diffraction study.
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页数：6
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