Ag(<sc>i</sc>)-catalyzed three-component radical cascade synthesis of 3-organoselenyl chromones from 2-methoxyaryl alkynones, Se powder and organic boronic acids

被引：2

作者：

Sun, Nan ^{[1
]}

Qiao, Zengguo ^{[1
]}

Liu, Xiaolong ^{[1
]}

Qiao, Zhi ^{[1
]}

Jin, Liqun ^{[1
]}

Hu, Xinquan ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2023年 / 47卷 / 47期

关键词：

SELENIUM POWDER; SCAFFOLD; ACCESS;

D O I：

10.1039/d3nj04463g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we present a new Ag(i)-catalyzed three-component radical cascade reaction for the construction of 3-organoselenyl chromones from 2-methoxyaryl alkynones, Se powder and organic boronic acids. With 20 mol% of AgNO3 as a catalyst, 10 mol% of SDS as an additive and under an O2 atmosphere in 1,4-dioxane, a wide range of multi-functionalized 3-organoselenyl chromones have been achieved in good to excellent yields. This protocol features easy availability of starting materials, simple operation, high step-economy and high structural diversity of products.

引用

页码：21670 / 21676

页数：7