Evaluation of a Bidentate 'Clamp-Like' Halogen-Bond Donor Motif Based on Iodonium(III) Moieties

被引：4

作者：

Reinhard, Dominik L. ^{[1
]}

Kutzinski, Dana ^{[1
]}

Hatta, Masahito ^{[1
]}

Engelage, Elric ^{[1
]}

Huber, Stefan M. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Fak Chem & Biochem, Univ Str 150, D-44801 Bochum, Germany

来源：

SYNLETT | 2024年 / 35卷 / 02期

关键词：

halogen bonding; hypervalent iodine; structure-activity relationship; organocatalysis; diaryliodonium; ONE-POT SYNTHESIS; DIARYLIODONIUM SALTS; SIGMA-HOLE; ORGANOCATALYSIS; CATALYST; INDOLES; OPTIMIZATION; IODINATION; CHEMISTRY; EFFICIENT;

D O I：

10.1055/a-2198-3914

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new motif for iodine(III)-based halogen-bond donors consisting of a 1,3-phenylene core and two cyclic five-membered diaryliodonium(III) wings was designed and its potential as a catalyst was evaluated. Its properties were analyzed in the solid state by X-ray crystallography and in solution by benchmark catalytic activation of a nitro Michael addition between 5-methoxyindole and trans-beta-nitrostyrene.

引用

页码：209 / 214

页数：6

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ccdc, CCDC 2298229 CONTAIN

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