Recent Advances in Nickel Catalyzed Asymmetric Acylation Reactions

被引：11

作者：

Zhang Yanyan ^{[1
]}

Zhang Zhuzhu ^{[1
]}

Zhu Shengqing ^{[1
]}

Chu Lingling ^{[1
]}

机构：

[1] Donghua Univ, Coll Chem & Chem Engn, Ctr Adv Low Dimens Mat, Shanghai 201620, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 03期

基金：

中国国家自然科学基金;

关键词：

nickel catalysis; asymmetric acylation; hydroacylation; alkene; STEREOSELECTIVE CONSTRUCTION; COUPLING SYNTHESIS; CARBON-CARBON; PHOTOREDOX; NI; CARBAMOYLATION; ARYLATION; KETONES;

D O I：

10.6023/cjoc202211032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral.proportional to-carbonyl compounds are important structural units in natural products and pharmaceuticals and versatile synthetic building blocks in organic synthesis. Transition metal-catalyzed asymmetric acylation reaction is one of the most straightforward methods for preparing these compounds. In particular, significant progress has been made in the area of nickel-catalyzed asymmetric acylation reaction, due to the unique properties of nickel catalysts. The latest progress of nickel-catalyzed asymmetric acylation reaction, including nickel-catalyzed asymmetric alkyl-acyl cross-coupling reaction, asymmetric hydroacylation of alkene and asymmetric acyl-functionalization alkene, is summarized.

引用

页码：1023 / 1035

页数：13

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