A new approach for producing methanol via process integration of vacuum residue gasification and NG reforming aiming at low CO2 emissions, an extensive techno-economic study

被引:0
作者
Al-Rowaili, Fayez Nasir [1 ,2 ]
Zahid, Umer [1 ,3 ]
Khalafalla, Siddig S. [1 ]
Jamal, Aqil [2 ]
Al-Mutairi, Eid M. [1 ,4 ,5 ]
机构
[1] King Fahd Univ Petr & Minerals, Chem Dept, Dhahran 31261, Saudi Arabia
[2] Saudi Aramco, Dhahran, Saudi Arabia
[3] King Fahd Univ Petr & Minerals KFUPM, Interdisciplinary Res Ctr Membranes & Water Secur, Dhahran 31261, Saudi Arabia
[4] King Fahd Univ Petr & Minerals, Interdisciplinary Res Ctr Refining & Adv Chem, Dhahran 31261, Saudi Arabia
[5] King Fahd Univ Petr & Minerals, Chem Engn Dept, Dhahran 31261, Saudi Arabia
关键词
Methanol; Carbon capture; Gasification; Dry reforming; Techno-economics; HYDROGEN-PRODUCTION; NATURAL-GAS; SIMULATION; OIL;
D O I
10.1016/j.ces.2023.119458
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This work proposed and analyzed critically two different novel processes to produce highly pure methanol from vacuum residue while reducing carbon discharge into the environment. The initial path (Case I) considered newly proposed heavy vacuum residue (VR) gasification in sequence with dry reforming of methane (DMR). Whereas the second pathway investigated a parallel integration of DMR and the gasification of VR (Case II). The two processes were compared in terms of CO2 emissions, energy consumption, energy efficiency, and environ -mental and economic impacts. The findings demonstrated that Case II yields a higher process energy efficiency than Case I. The unit cost of methanol product for Case II is 342.2 $/t of methanol which is almost 7 % lower compared to Case I. Based on environmental analysis, Case II exhibits smaller carbon discharge of about 0.74 kg of CO2/kg of methanol.
引用
收藏
页数:14
相关论文
共 43 条
[11]  
[Anonymous], 2018, Global Energy Statistical Yearbook 2018
[12]   Combustion performance and emissions of petrodiesel and biodiesels based on various vegetable oils in a semi industrial boiler [J].
Bazooyar, Bahamin ;
Ghorbani, Afshin ;
Shariati, Ahmad .
FUEL, 2011, 90 (10) :3078-3092
[13]   Thermodynamic analysis of carbon dioxide hydrogenation to formic acid and methanol [J].
Bello, T. O. ;
Bresciani, A. E. ;
Nascimento, C. A. O. ;
Alves, R. M. B. .
CHEMICAL ENGINEERING SCIENCE, 2021, 239
[14]   Experimental and theoretical study on the characteristics of vacuum residue gasification in an entrained-flow gasifier [J].
Choi, Young-Chan ;
Lee, Jae-Goo ;
Yoon, Sang-Jun ;
Park, Moon-Hee .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2007, 24 (01) :60-66
[15]  
Council W.E., 2013, World energy scenarios
[16]   Power-to-liquidviasynthesis of methanol, DME or Fischer-Tropsch-fuels: a review [J].
Dieterich, Vincent ;
Buttler, Alexander ;
Hanel, Andreas ;
Spliethoff, Hartmut ;
Fendt, Sebastian .
ENERGY & ENVIRONMENTAL SCIENCE, 2020, 13 (10) :3207-3252
[17]   Simulation and optimization of a methanol synthesis process from different biogas sources [J].
dos Santos, Rafael Oliveira ;
Santos, Lizandro de Sousa ;
Prata, Diego Martinez .
JOURNAL OF CLEANER PRODUCTION, 2018, 186 :821-830
[18]   Design, techno-economic evaluation, and optimisation of renewable methanol plant model: Finland case study [J].
Emebu, Samuel ;
Martinez, Clara Mendoza ;
Omoregbe, Osaze ;
Mankonen, Aleksi ;
Ogbuoji, Ebuka A. ;
Shaikh, Ibrahim ;
Pettersen, Even ;
Kubalcik, Marek ;
Okieimen, Charity .
CHEMICAL ENGINEERING SCIENCE, 2023, 278
[19]   Methanol production in an optimized dual-membrane fixed-bed reactor [J].
Farsi, M. ;
Jahanmiri, A. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2011, 50 (11-12) :1177-1185
[20]   Gasification of a Heavy Fuel Oil: A Parametric Study on Energy and Exergy Analysis for Different Gasifying Agents [J].
Fasih, H. F. ;
Ghassemi, H. ;
Shahi, H. K. Mazrae .
PETROLEUM CHEMISTRY, 2021, 61 (02) :162-171