Metal organic framework derived cobalt tetroxide for enhanced electrochemical hydrogen evolution reaction

被引:5
作者
Wang, Jianxing [1 ]
Yan, Bo [1 ]
Fang, Bo [2 ]
Jian, Zicong [3 ]
机构
[1] Sun Yat sen Univ, Sch Mat Sci & Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China
[2] Guangdong One Nano Technol Co Ltd, Huizhou 516029, Peoples R China
[3] Huizhou Univ, Sch Chem & Mat Engn, Huizhou 516007, Peoples R China
关键词
Microstructure; Electrocatalyst; Hydrogen evolution reaction; EFFICIENT; POLYHEDRA;
D O I
10.1016/j.matlet.2022.133448
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Herein, we report a self-supporting electrode fabricated by calcining Co-MOF on nickel foam (Co3O4@NF) for hydrogen evolution reaction (HER). Consequently, in alkaline electrolyte, Co3O4@NF exhibits excellent catalytic activity and fast kinetics towards HER, requiring only small overpotentials of 131 and 224 mV to provide current densities of 10 and 100 mA cm-2, and good durability at 10 mA cm-2 for 50 h. This is attributed to the rough surface of Co3O4@NF, which provides much active sites and therefore facilitates the HER process.
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页数:4
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