Unveiling All-Optical Switching Phenomenon in Anthracene Derivatives: A Comprehensive Study on Optical and Nonlinear Optical Multifunctionality

被引:5
|
作者
Szukalski, Adam [1 ]
Zajac, Dorota [1 ]
Pardus, Natasza [1 ]
Karout, Houda El [2 ,3 ]
Krawczyk, Przemyslaw [4 ]
Sahraoui, Bouchta [3 ]
机构
[1] Wroclaw Univ Sci & Technol, Inst Adv Mat, Wybrzeze Wyspianskiego 27, PL-50370 Wroclaw, Poland
[2] Univ Angers, CNRS, MOLTECH ANJOU, SFR MATRIX, F-49000 Angers, France
[3] Univ Angers, LPHIA, SFR MATRIX, F-49000 Angers, France
[4] Nicolaus Copernicus Univ, Fac Pharm, Coll Med, Kurpinskiego 5, PL-85950 Bydgoszcz, Poland
关键词
all-optical switching; anthracene derivatives; laser spectroscopy; nonlinear optics; TD-DFT; 2ND-HARMONIC GENERATION; 3RD-HARMONIC GENERATION; FLUORESCENT-PROBE; 2ND-ORDER; EFFICIENCY; NAPHTHALENE; PERFORMANCE; ORGANOGEL; STATES;
D O I
10.1002/adom.202303156
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, it is considered three anthracene derivatives, characterized meticulously in terms of their chemical structure and product purity. Extensive quantum chemical calculations are conducted to elucidate their optical and nonlinear optical properties, shedding light on the mechanism of photoinduced conformational transformation, a pivotal discovery in this research. Experimental analyses encompassed fundamental optical properties and advanced nonlinear optical phenomena, including z-scan experiments, second harmonic generation (SHG), and third harmonic generation (THG). Remarkably, a groundbreaking all-optical switching phenomenon in these materials is experimentally validated, marking a significant advancement and contributing to their potential applications. Three anthracene derivatives through quantum chemical and experimental physics insights is investigated, which revealed all-optical switching phenomenon together with its mechanism description. Using precise calculations and experimental analyses it is delve into fundamental traits and advanced nonlinear optical phenomena, validating groundbreaking all-optical switching in these materials-a significant advance in anthracene-based materials research with potential applications. image
引用
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页数:18
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