Recent progress in CO2 conversion into organic chemicals by molecular catalysis

被引:58
作者
Song, Qing-Wen [1 ]
Ma, Ran [4 ]
Liu, Ping [1 ]
Zhang, Kan [1 ]
He, Liang-Nian [2 ,3 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[3] Nankai Univ, Inst Elemento Organ Chem, Tianjin 300071, Peoples R China
[4] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710021, Peoples R China
基金
中国国家自然科学基金;
关键词
ALKYLIDENE CYCLIC CARBONATES; IONIC LIQUID; PROPARGYLIC ALCOHOLS; DIMETHYL CARBONATE; ALTERNATING COPOLYMERIZATION; ATMOSPHERIC-PRESSURE; AMBIENT CONDITIONS; CASCADE REACTION; SUSTAINABLE CONVERSION; EFFICIENT CONVERSION;
D O I
10.1039/d3gc01892j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemical conversion of carbon dioxide (CO2) into high-value chemicals or fuels is exceedingly attractive due to its green and sustainable features. However, practical technologies on scale utilization of CO2 are few, and nearly no new industrial processes on the topic have emerged over the years. The current bottlenecks, e.g., low efficiency and atom economy, seriously restrict the process development. In recent studies, the catalytic activation of CO2 and/or substrate has been revealed to play a significant role in the promotion of CO2 functionalization to valuable chemicals, including the representative reactions of epoxides/propargyl alcohols/propargylamines with CO2, multicomponent cascade reactions, N-formylation of amines with CO2 and hydrosilanes, and unactivated C-H bond carboxylation. Herein, recent significant advances (2017-2022) on the effective chemical fixation of CO2 through molecular activation or synergistic activation strategies in homogeneous systems are presented. The superiority of molecular activation in thermochemical catalysis is shown in a wide range of CO2 transformations. Through CO2/substrate activation and catalysis with well-developed metal or organocatalysts, valuable chemicals are successfully attained with great efficiency. The new progress will provide significant guidance to promote the effective and sustainable utilization of CO2.
引用
收藏
页码:6538 / 6560
页数:23
相关论文
共 176 条
  • [61] Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide
    Julia-Hernandez, Francisco
    Moragas, Toni
    Cornella, Josep
    Martin, Ruben
    [J]. NATURE, 2017, 545 (7652) : 84 - +
  • [62] CO2-fixation into cyclic and polymeric carbonates: principles and applications
    Kamphuis, Aeilke J.
    Picchioni, Francesco
    Pescarmona, Paolo P.
    [J]. GREEN CHEMISTRY, 2019, 21 (03) : 406 - 448
  • [63] N-Heterocyclic Carbenes as Efficient Organocatalysts for CO2 Fixation Reactions
    Kayaki, Yoshihito
    Yamamoto, Masafumi
    Ikariya, Takao
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (23) : 4194 - 4197
  • [64] Highly active dinuclear cobalt complexes for solvent-free cycloaddition of CO2 to epoxides at ambient pressure
    Khattak, Zafar A. K.
    Younus, Hussein A.
    Ahmad, Nazir
    Ullah, Habib
    Suleman, Suleman
    Hossain, Md. Shahadat
    Elkadi, Mirella
    Verpoort, Francis
    [J]. CHEMICAL COMMUNICATIONS, 2019, 55 (57) : 8274 - 8277
  • [65] Efficient Aluminum Catalysts for the Chemical Conversion of CO2 into Cyclic Carbonates at Room Temperature and Atmospheric CO2 Pressure
    Kim, Yoseph
    Hyun, Kyunglim
    Ahn, Duseong
    Kim, Ran
    Park, Myung Hwan
    Kim, Youngjo
    [J]. CHEMSUSCHEM, 2019, 12 (18) : 4211 - 4220
  • [66] A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure
    Kimura, Toshihiro
    Kamata, Keigo
    Mizuno, Noritaka
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (27) : 6700 - 6703
  • [67] Highly Active Chromium Complexes Supported by Constrained Schiff-Base Ligands for Cycloaddition of Carbon Dioxide to Epoxides
    Kiriratnikom, Jiraya
    Laiwattanapaisarn, Nattiya
    Vongnam, Kunnigar
    Thavornsin, Nopparat
    Sae-ung, Pornpen
    Kaeothip, Sophon
    Euapermkiati, Anucha
    Namuangruk, Supawadee
    Phomphrai, Khamphee
    [J]. INORGANIC CHEMISTRY, 2021, 60 (09) : 6147 - 6151
  • [68] Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry
    Klankermayer, Juergen
    Wesselbaum, Sebastian
    Beydoun, Kassem
    Leitner, Walter
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (26) : 7296 - 7343
  • [69] Green Catalytic Process for Cyclic Carbonate Synthesis from Carbon Dioxide under Mild Conditions
    Lang, Xian-Dong
    He, Liang-Nian
    [J]. CHEMICAL RECORD, 2016, 16 (03) : 1337 - 1352
  • [70] Cascade Strategy for Atmospheric Pressure CO2 Fixation to Cyclic Carbonates via Silver Sulfadiazine and Et4NBr Synergistic Catalysis
    Li, Jing-Yuan
    Han, Li-Hua
    Xu, Qin-Chao
    Song, Qing-Wen
    Liu, Ping
    Zhang, Kan
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (03): : 3378 - 3388