Recent progress in CO2 conversion into organic chemicals by molecular catalysis

被引:58
作者
Song, Qing-Wen [1 ]
Ma, Ran [4 ]
Liu, Ping [1 ]
Zhang, Kan [1 ]
He, Liang-Nian [2 ,3 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[3] Nankai Univ, Inst Elemento Organ Chem, Tianjin 300071, Peoples R China
[4] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710021, Peoples R China
基金
中国国家自然科学基金;
关键词
ALKYLIDENE CYCLIC CARBONATES; IONIC LIQUID; PROPARGYLIC ALCOHOLS; DIMETHYL CARBONATE; ALTERNATING COPOLYMERIZATION; ATMOSPHERIC-PRESSURE; AMBIENT CONDITIONS; CASCADE REACTION; SUSTAINABLE CONVERSION; EFFICIENT CONVERSION;
D O I
10.1039/d3gc01892j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemical conversion of carbon dioxide (CO2) into high-value chemicals or fuels is exceedingly attractive due to its green and sustainable features. However, practical technologies on scale utilization of CO2 are few, and nearly no new industrial processes on the topic have emerged over the years. The current bottlenecks, e.g., low efficiency and atom economy, seriously restrict the process development. In recent studies, the catalytic activation of CO2 and/or substrate has been revealed to play a significant role in the promotion of CO2 functionalization to valuable chemicals, including the representative reactions of epoxides/propargyl alcohols/propargylamines with CO2, multicomponent cascade reactions, N-formylation of amines with CO2 and hydrosilanes, and unactivated C-H bond carboxylation. Herein, recent significant advances (2017-2022) on the effective chemical fixation of CO2 through molecular activation or synergistic activation strategies in homogeneous systems are presented. The superiority of molecular activation in thermochemical catalysis is shown in a wide range of CO2 transformations. Through CO2/substrate activation and catalysis with well-developed metal or organocatalysts, valuable chemicals are successfully attained with great efficiency. The new progress will provide significant guidance to promote the effective and sustainable utilization of CO2.
引用
收藏
页码:6538 / 6560
页数:23
相关论文
共 176 条
[111]   2-Picolinic acid as a naturally occurring hydrogen bond donor for the preparation of cyclic carbonates from terminal/internal epoxides and CO2 [J].
Rostami, Ali ;
Ebrahimi, Amirhossein ;
Al-Jassasi, Mohammed ;
Mirzaei, Saber ;
Al-Harrasi, Ahmed .
GREEN CHEMISTRY, 2022, 24 (23) :9069-9083
[112]   An Electrostatically Enhanced Phenol as a Simple and Efficient Bifunctional Organocatalyst for Carbon Dioxide Fixation [J].
Rostami, Ali ;
Mahmoodabadi, Mohammadali ;
Ebrahimi, Amir Hossein ;
Khosravi, Hormoz ;
Al-Harrasi, Ahmed .
CHEMSUSCHEM, 2018, 11 (24) :4262-4268
[113]   Highly efficient synthesis of alkylidene cyclic carbonates from low concentration CO2 using hydroxyl and azolate dual functionalized ionic liquids [J].
Shi, Guiling ;
Zhai, Ran ;
Li, Haoran ;
Wang, Congmin .
GREEN CHEMISTRY, 2021, 23 (01) :592-596
[114]   Plasma technology - a novel solution for CO2 conversion? [J].
Snoeckx, Ramses ;
Bogaerts, Annemie .
CHEMICAL SOCIETY REVIEWS, 2017, 46 (19) :5805-5863
[115]   Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2 [J].
Song, Lei ;
Wang, Wei ;
Yue, Jun-Ping ;
Jiang, Yuan-Xu ;
Wei, Ming-Kai ;
Zhang, Hai-Peng ;
Yan, Si-Shun ;
Liao, Li-Li ;
Yu, Da-Gang .
NATURE CATALYSIS, 2022, 5 (09) :832-838
[116]   Pd-catalyzed carbonylation of aryl C-H bonds in benzamides with CO2 [J].
Song, Lei ;
Cao, Guang-Mei ;
Zhou, Wen-Jun ;
Ye, Jian-Heng ;
Zhang, Zhen ;
Tian, Xing-Yang ;
Li, Jing ;
Yu, Da-Gang .
ORGANIC CHEMISTRY FRONTIERS, 2018, 5 (13) :2086-2090
[117]   Catalytic Lactonization of Unactivated Aryl C-H Bonds with CO2: Experimental and Computational Investigation [J].
Song, Lei ;
Zhu, Lei ;
Zhang, Zhen ;
Ye, Jian-Heng ;
Yang, Si-Shun ;
Han, Jie-Lian ;
Yin, Zhu-Bao ;
Lan, Yu ;
Yu, Da-Gang .
ORGANIC LETTERS, 2018, 20 (13) :3776-3779
[118]   Efficient, selective and sustainable catalysis of carbon dioxide [J].
Song, Qing-Wen ;
Zhou, Zhi-Hua ;
He, Liang-Nian .
GREEN CHEMISTRY, 2017, 19 (16) :3707-3728
[119]   Thermodynamically Favorable Synthesis of 2-Oxazolidinones through Silver-Catalyzed Reaction of Propargylic Alcohols, CO2, and 2-Aminoethanols [J].
Song, Qing-Wen ;
Zhou, Zhi-Hua ;
Wang, Mei-Yan ;
Zhang, Kan ;
Liu, Ping ;
Xun, Jia-Yao ;
He, Liang-Nian .
CHEMSUSCHEM, 2016, 9 (16) :2054-2058
[120]   Robust Silver(I) Catalyst for the Carboxylative Cyclization of Propargylic Alcohols with Carbon Dioxide under Ambient Conditions [J].
Song, Qing-Wen ;
He, Liang-Nian .
ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (08) :1251-1258