Surface Modulation via Conjugated Bithiophene Ammonium Salt for Efficient Inverted Perovskite Solar Cells

被引：7

作者：

Zhang, Xin ^{[1
,2
,3
,4
,5
]}

Eurelings, Stijn ^{[7
]}

Bracesco, Andrea ^{[7
]}

Song, Wenya ^{[3
,4
,5
,6
]}

Lenaers, Stijn ^{[6
]}

Van Gompel, Wouter ^{[6
]}

Krishna, Anurag ^{[4
,5
,6
]}

Aernouts, Tom ^{[4
,5
,6
]}

Lutsen, Laurence ^{[5
,6
]}

Vanderzande, Dirk ^{[5
,6
]}

Creatore, Mariadriana ^{[7
,8
]}

Zhan, Yiqiang ^{[1
,2
]}

Kuang, Yinghuan ^{[4
,5
,6
]}

Poortmans, Jef ^{[3
,4
,5
,6
]}

机构：

[1] Fudan Univ, Ctr Micro Nano Syst, Sch Informat Sci & Technol SIST, Shanghai 200433, Peoples R China

[2] Fudan Univ, Acad Engn & Technol FAET, Shanghai 200433, Peoples R China

[3] Katholieke Univ Leuven, Dept Elect Engn ESAT, B-3001 Leuven, Belgium

[4] Imec, Imo Imomec, Thin Film PV Technol Partner Solliance, B-3600 Genk, Belgium

[5] Imo Imomec, EnergyVille, B-3600 Genk, Belgium

[6] Hasselt Univ, Imo Imomec, B-3500 Hasselt, Belgium

[7] Eindhoven Univ Technol TU E, Dept Appl Phys & Sci Educ, Plasma & Mat Proc, NL-5600 MB Eindhoven, Netherlands

[8] Eindhoven Inst Renewable Energy Syst EIRES, NL-5600 MB Eindhoven, Netherlands

来源：

ACS APPLIED MATERIALS & INTERFACES | 2023年 / 15卷 / 40期

基金：

中国国家自然科学基金;

关键词：

operational stability; burn-in effect; surfacemodulation; perovskite solar cells; sputtered nickeloxide; LONG-TERM STABILITY; DEFECT PASSIVATION; PERFORMANCE; INTERFACES; POLYMER;

D O I：

10.1021/acsami.3c08119

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The metal halide perovskite absorbers are prone to surface defects, which severely limit the power conversion efficiencies (PCEs) and the operational stability of the perovskite solar cells (PSCs). Herein, trace amounts of bithiophene propylammonium iodide (bi-TPAI) are applied to modulate the surface properties of the gas-quenched perovskite. It is found that the bi-TPAI surface treatment has negligible impact on the perovskite morphology, but it can induce a defect passivation effect and facilitate the charge carrier extraction, contributing to the gain in the open-circuit voltage (V oc) and fill factor. As a result, the PCE of the gas-quenched sputtered NiO x -based inverted PSCs is enhanced from the initial 20.0% to 22.0%. Most importantly, the bi-TPAI treatment can largely alleviate or even eliminate the burn-in process during the maximum power point tracking measurement, improving the operational stability of the devices.

引用

页码：46803 / 46811

页数：9

共 44 条

[1] Inorganic hole transport layers in inverted perovskite solar cells: A review [J].

Arumugam, Gowri Manohari ;

Karunakaran, Santhosh Kumar ;

Liu, Chong ;

Zhang, Cuiling ;

Guo, Fei ;

Wu, Shaohang ;

Mai, Yaohua .

NANO SELECT, 2021, 2 (06) :1081-1116

[2] Damp heat-stable perovskite solar cells with tailored-dimensionality 2D/3D heterojunctions [J].

Azmi, Randi ;

Ugur, Esma ;

Seitkhan, Akmaral ;

Aljamaan, Faisal ;

Subbiah, Anand S. ;

Liu, Jiang ;

Harrison, George T. ;

Nugraha, Mohamad, I ;

Eswaran, Mathan K. ;

Babics, Maxime ;

Chen, Yuan ;

Xu, Fuzong ;

Allen, Thomas G. ;

Rehman, Atteq Ur ;

Wang, Chien-Lung ;

Anthopoulos, Thomas D. ;

Schwingenschlogl, Udo ;

De Bastiani, Michele ;

Aydin, Erkan ;

De Wolf, Stefaan .

SCIENCE, 2022, 376 (6588) :73-+

[3] Overcoming Redox Reactions at Perovskite-Nickel Oxide Interfaces to Boost Voltages in Perovskite Solar Cells [J].

Boyd, Caleb C. ;

Shallcross, R. Clayton ;

Moot, Taylor ;

Kerner, Ross ;

Bertoluzzi, Luca ;

Onno, Arthur ;

Kavadiya, Shalinee ;

Chosy, Cullen ;

Wolf, Eli J. ;

Werner, Jeremie ;

Raiford, James A. ;

de Paula, Camila ;

Palmstrom, Axel F. ;

Yu, Zhengshan J. ;

Berry, Joseph J. ;

Bent, Stacey F. ;

Holman, Zachary C. ;

Luther, Joseph M. ;

Ratcliff, Erin L. ;

Armstrong, Neal R. ;

McGehee, Michael D. .

JOULE, 2020, 4 (08) :1759-1775

[4] A novel quadruple-cation absorber for universal hysteresis elimination for high efficiency and stable perovskite solar cells [J].

Bu, Tongle ;

Liu, Xueping ;

Zhou, Yuan ;

Yi, Jianpeng ;

Huang, Xin ;

Luo, Long ;

Xiao, Junyan ;

Ku, Zhiliang ;

Peng, Yong ;

Huang, Fuzhi ;

Cheng, Yi-Bing ;

Zhong, Jie .

ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (12) :2509-2515

[5] Efficient and stable inverted perovskite solar cells with very high fill factors via incorporation of star-shaped polymer [J].

Cao, Qi ;

Li, Yongjiang ;

Zhang, Hong ;

Yang, Jiabao ;

Han, Jian ;

Xu, Ting ;

Wang, Shuangjie ;

Wang, Zishuai ;

Gao, Bingyu ;

Zhao, Junsong ;

Li, Xiaoqiang ;

Ma, Xiaoyan ;

Zakeeruddin, Shaik Mohammed ;

Sha, Wei E., I ;

Li, Xuanhua ;

Graetzel, Michael .

SCIENCE ADVANCES, 2021, 7 (28)

[6] Highly enhanced long time stability of perovskite solar cells by involving a hydrophobic hole modification layer [J].

Chen, Cong ;

Li, Hao ;

Jin, Junjie ;

Cheng, Yu ;

Liu, Dali ;

Song, Hongwei ;

Dai, Qilin .

NANO ENERGY, 2017, 32 :165-173

[7] Simultaneously Modifying Hole Transport Material and Perovskite via a Crown Ether-Based Semiconductor Toward Efficient and Stable Perovskite Solar Cells [J].

Chen, Kaixing ;

Lu, Huiqiang ;

Yang, Yang ;

Li, Shufang ;

Jia, Kangkang ;

Wu, Fei ;

Zhu, Linna .

SOLAR RRL, 2023, 7 (04)

[8] Thermally stable methylammonium-free inverted perovskite solar cells with Zn2+ doped CuGaO2 as efficient mesoporous hole-transporting layer [J].

Chen, Yu ;

Yang, Zhou ;

Jia, Xuguang ;

Wu, Yihui ;

Yuan, Ningyi ;

Ding, Jianning ;

Zhang, Wen-Hua ;

Liu, Shengzhong .

NANO ENERGY, 2019, 61 :148-157

[9] Directing the Self-Assembly of Conjugated Organic Ammonium Cations in Low-Dimensional Perovskites by Halide Substitution [J].

Denis, Paul-Henry ;

Mertens, Martijn ;

Van Gompel, Wouter T. M. ;

Van Hecke, Kristof ;

Ruttens, Bart ;

D'Haen, Jan ;

Lutsen, Laurence ;

Vanderzande, Dirk .

CHEMISTRY OF MATERIALS, 2021, 33 (13) :5177-5188

[10] Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells [J].

Domanski, Konrad ;

Roose, Bart ;

Matsui, Taisuke ;

Saliba, Michael ;

Turren-Cruz, Silver-Hamill ;

Correa-Baena, Juan-Pablo ;

Roldan-Carmona, Cristina ;

Richardson, Giles ;

Foster, Jamie M. ;

De Angelis, Filippo ;

Ball, James M. ;

Petrozza, Annamaria ;

Mine, Nicolas ;

Nazeeruddin, Mohammad K. ;

Tress, Wolfgang ;

Gratzel, Michael ;

Steiner, Ullrich ;

Hagfeldt, Anders ;

Abate, Antonio .

ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (02) :604-613

← 1 2 3 4 5 →