Tunable blue-green emission properties of Tb3+ doped barium tantalate phosphor

The TTB (tetragonal tungsten bronze) crystal structure with the general formula of A(4)B(2)C(4)M(10)O(30) has three tunnels (A, B, C) of different coordination numbers with a corner-shared octahedral formation. Thanks to these properties, the TTB structure enables various RE ion substitutions and different physical properties to emerge. A series of green-emitting Tb3+ doped barium tantalate phosphors with TTB-type structure between 0.25 and 5 mol% obtained by the solid-state reaction route is reported. The structure of Tb3+ doped TTB-BaTa2O6 was identified by XRD and SEM-EDS analyses. PL relative emission intensity increased from 0.25 to 0.5 mol% and then decreased due to concentration quenching. Depending on the increasing concentration, the colour of the luminescence of BaTa2O6:Tb3+ phosphor can be tuned from blue to green through a cross-relaxation process, where a dipole-dipole energy transfer occurs between two nearby Tb3+ ions. The PL emission of the BaTa2O6:Tb3+ in the CIE diagram tended towards blue to green with the increase in Tb3+ concentration. PL decay profiles of the D-5(3) and D-5(4) states have a double exponential. The observed lifetimes of the D-5(3) state decrease as the decay profiles of the D-5(4) state exhibit a stable tendency. Based on the cross-relaxation process, the quantum efficiency (& eta;(QE)) of the phosphor was evaluated, and the & eta;(QE) of the D-5(3) state with the increase of Tb3+ concentration between 0.25 and 5 mol% varied from 61.63 to 40.85%, respectively.