Critical Review of Fluorinated Electrolytes for High-Performance Lithium Metal Batteries

被引：90

作者：

Li, Zhongzhe ^{[1
]}

Chen, Yufang ^{[1
]}

Yun, Xiaoru ^{[1
]}

Gao, Peng ^{[2
]}

Zheng, Chunman ^{[1
]}

Xiao, Peitao ^{[1
,3
]}

机构：

[1] Natl Univ Def Technol, Coll Aerosp Sci & Engn, Changsha 410073, Peoples R China

[2] Hunan Univ Changsha, Coll Mat Sci & Engn, Hunan Joint Int Lab Adv Mat & Technol Clean Energy, Hunan Prov Key Lab Adv Carbon Mat & Appl Technol, Changsha 410082, Peoples R China

[3] Natl Univ Def Technol, Sci & Technol Adv Ceram Fibers & Composite Lab, Changsha 410073, Hunan, Peoples R China

来源：

ADVANCED FUNCTIONAL MATERIALS | 2023年 / 33卷 / 32期

关键词：

electrode-electrolyte interphases; fluorinated electrolytes; lithium dendrites; lithium metal batteries; ORTHOFORMATE-BASED ELECTROLYTES; ION BATTERIES; LI; LIQUID; CARBONATE; ANODES; SALT; ADDITIVES; LIBOB; INTERPHASES;

D O I：

10.1002/adfm.202300502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium metal batteries (LMBs), due to their ultra-high energy density, are attracting tremendous attentions. However, their commercial application is severely impeded by poor safety and unsatisfactory cycling stability, which are induced by lithium dendrites, side reactions, and inferior anodic stability. Electrolytes, as the indispensable and necessary components in lithium metal batteries, play a crucial role in regulating the electrochemical performance of LMBs. Recently, the fluorinated electrolytes are widely investigated in high-performance LMBs. Thus, the design strategies of fluorinated electrolytes are thoroughly summarized, including fluorinated salts, fluorinated solvents, and fluorinated additives in LMBs, and insights of the fluorinated components in suppressing lithium dendrites, improving anodic stability and cycling stability. Finally, an outlook with several design strategies and challenges will be proposed for novel fluorinated electrolytes.

引用

页数：33

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