Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands

被引：1

作者：

Makarevich, J. E. ^{[1
]}

Ogarkova, N. K. ^{[1
]}

Sosunov, E. A. ^{[1
]}

Sulimova, O. V. ^{[1
]}

Skabitsky, I. V. ^{[1
]}

Popova, A. S. ^{[1
]}

Panina, M. V. ^{[1
]}

Nesterenko, M. Yu. ^{[1
]}

Vargaftik, M. N. ^{[1
]}

Yakushev, I. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 09期

关键词：

heterometallic complexes; palladium; cyclometalation; carboxylates; binuclear compounds; synthesis; 2-phenylpyridine; X-ray diffraction; CRYSTAL-STRUCTURE; TRINUCLEAR COMPLEXES; ACETATE; BONDS; MN; NI; CO;

D O I：

10.1134/S0036023623601708

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New bimetallic pivalate Pd(II) complex [PdNi((OOCBu)-Bu-t)(4)((HOOCBu)-Bu-t)] (I) has been synthesized from [PdNi(OOCMe)(4)] and used as a starting reagent in a further complexation reaction. Cyclometallated binuclear carboxylate palladium complexes [(OOCMe)Pd(2-phpy)](2) (II) and [((OOCBu)-Bu-t)Pd(2-phpy)](2) (III) have been obtained by the reaction between heterometallic compounds [Pd(OOCR)(4)Ni] (R = Me, Bu-t) and 2-phenylpyridine (2-phpy). The reaction proceeds at room temperature under mild conditions. All the compounds obtained have been isolated in crystalline form from a medium of nonpolar solvents, characterized by single-crystal X-ray diffraction analysis, and deposited at the Cambridge Crystallographic Data Center (CCDC nos. 2256606 for I, 2247942 for II, and 2247943 for III).

引用

页码：1217 / 1227

页数：11

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