Organic Photovoltaic Catalyst with σ-π Anchor for High-Performance Solar Hydrogen Evolution

Efficient in situ deposition of metallic cocatalyst, like zero-valent platinum (Pt), on organic photovoltaic catalysts (OPCs) is the prerequisite for their high catalytic activities. Here we develop the OPC (Y6CO), by introducing carbonyl in the core, which is available to sigma-pi coordinate with transition metals, due to the high-energy empty pi* orbital of carbonyl. Y6CO exhibits a stronger capability to anchor Pt species and reduce them to metallic state, resulting in more Pt-0 deposition, relative to the control OPC without the central sigma-pi anchor. Single-component and heterojunction nanoparticles (NPs) employing Y6CO show enhanced average hydrogen evolution rates of 230.98 and 323.22 mmol h(-1) g([OPC])(-1), respectively, under AM 1.5G, 100 mW cm(-2) for 10 h, and heterojunction NPs yield the external quantum efficiencies of ca. 10 % in 500-800 nm. This work demonstrates that sigma-pi anchoring is one efficient strategy for integrating metallic cocatalyst and OPC for high-performance photocatalysis.