Enhanced performance of heterogeneous fenton-like Co-Cu catalysts for metronidazole degradation: Ethylene glycol as a superior fabrication solvent

被引：4

作者：

Liu, Liang ^{[1
]}

Li, Jiajun ^{[1
]}

Guo, Xiaoxi ^{[1
,2
]}

Wu, Hongyang ^{[3
]}

Wu, Jiabao ^{[4
]}

Dong, Yongzhen ^{[1
]}

Li, Yunfang ^{[1
]}

Lu, Yao ^{[2
]}

机构：

[1] Henan Univ Sci & Technol, Sch Chem & Chem Engn, Luoyang 471000, Peoples R China

[2] Queen Mary Univ London, Sch Phys & Chem Sci, Dept Chem, London E1 4NS, England

[3] Luoyang Inst Sci & Technol, Sch Environm Engn & Chem, Luoyang 471000, Peoples R China

[4] Wanhua Chem Grp Co Ltd, Yantai 265505, Peoples R China

来源：

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2023年 / 11卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Co-Cu catalysts; Metronidazole degradation; Fenton -like reaction; Hydroxyl radical; Ethylene glycol solvent; OXIDATION; ACTIVATION; HYDROXIDES; REDUCTION; CARBONATE; KINETICS; CHLORIDE; REMOVAL; SULFATE; IONS;

D O I：

10.1016/j.jece.2023.110597

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

This study addresses the gap in understanding of fabrication solvent influence on Cu-Co catalyst performance for MNZ degradation. By synthesizing recyclable Cu-Co catalysts using the co-precipitation method, the study in-vestigates the impact of ethylene glycol (EG) solvent compared to conventional water (H2O) solvent. The opti-mized operational parameters resulted in stable and high MNZ degradation efficiency (above 90 % removal) with twice-feeding of 1600 ppm H2O2, pH similar to 7.15, and 50 degrees C. The use of EG solvent enhances catalyst surface area, exposing more active sites with higher Cu+ and Cu2+ content, which incorporated in CoO6 environment with promoted redox property to facilitate H(2)O(2)reaction and center dot OH production. This research contributes valuable insights into catalyst design and optimization, highlighting the potential of EG solvent for industrial application in antibiotic organic pollutant remediation.

引用

页数：12

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