Structure and magnetism of novel high-entropy rare-earth iron garnet ceramics

被引:23
作者
Chen, Dongyang [1 ]
Yang, Yujie [1 ]
Chen, Congliang [1 ]
Meng, Yuting [1 ]
Zhang, Yingming [1 ]
Zhang, Cong [1 ]
机构
[1] Anhui Univ, Engn Technol Res Ctr Magnet Mat, Sch Mat Sci & Engn, Hefei 230601, Anhui, Peoples R China
关键词
High entropy ceramics; Garnets; X-ray diffraction; Magnetism; YIG; ALLOY; ND;
D O I
10.1016/j.ceramint.2022.11.161
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A new type of high-entropy rare-earth iron garnet ceramic structure (Gd0.2Dy0.2Er0.2Y0.2RE0.2)3Fe5O12 (RE = Sm, Eu, Tm, Yb) powders were synthesised using a solid-phase method. In addition, the microstructure and magnetic properties of the (Gd0.2Dy0.2Er0.2Y0.2RE0.2)3Fe5O12 (RE = Sm, Eu, Tm, Yb) powders were evaluated. The (Gd0.2Dy0.2Er0.2Y0.2RE0.2)3Fe5O12 (RE = Sm, Eu, Tm, Yb) ceramics presented garnet crystal structure (Ia-3d), and their lattice parameters ranged between 12.3921 and 12.3644 A. Moreover, the saturation magnetisation (Ms) and coercivity (Hc) of the ceramics ranged between 12.29 and 13.27 emu/g and between 18.46 and 19.87 Oe, respectively. The Ms and Hc values of the samples were comparable, indicating that magnetism of high-entropy rare-earth iron garnet ceramic can be fine-tuned by customising their composition. The magnetic properties of high-entropy rare-earth iron garnet ceramics have not yet been elucidated; however, previous studies have demonstrated that high-entropy rare-earth iron garnet ceramics present unique magnetism.
引用
收藏
页码:9862 / 9867
页数:6
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