Nonfullerene Organic Solar Cells with 18.17% Efficiency Obtained Using a V2C/PEDOT:PSS Composite Hole-Transport Layer

被引：10
作者：
Gu, Qun [1 ,2 ]
Wang, Jie [2 ]
Peng, Ruixiang [2 ,3 ]
Song, Wei [2 ]
Zhou, Rong [1 ,2 ]
Ge, Ziyi [2 ,3 ]
机构：
[1] Ningbo Univ, Fac Informat Sci & Engn, Ningbo 315211, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Engn Res Ctr Energy Optoelect Mat &, Ningbo 315201, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
来源：
ACS APPLIED ENERGY MATERIALS | 2023年 / 6卷 / 03期
基金：
中国国家自然科学基金;
关键词：
composite film; 2D materials (V2C); hole-transport layer; interface engineering; electrical conductivity; organic solar cells; INTERLAYER; CATHODE; FILMS;
D O I：
10.1021/acsaem.2c03883
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
More efficient promotion of charge collection and transport is an essential factor to achieve high efficiency of the devices; however, the matching of energy level between the PEDOT:PSS hole-transport layer (HTL) and indium tin oxide (ITO) is not perfect, which limits the efficiency of exciton utilization. Herein, the composite HTL of V2C/PEDOT:PSS is formed using two-dimensional (2D) conducting material V2C and PEDOT:PSS, which shows a lower work function (WF) and higher conductivity than the pure PEDOT:PSS films and shows advantages to improve the Ohmic contact between the active layer and electrode. The efficiency of the devices prepared with the V2C (0.075 mg/mL)/PEDOT:PSS composite HTL based on the nonfullerene PM6:BTP-eC9 system reaches 18.17%. The enhancement in performance can be ascribed to the interaction between the functional groups of V2C and PEDOT:PSS, as well as the increase in the overall hole-transport layer conductivity. The method proposed in this study to prepare this V2C/PEDOT:PSS composite HTL improves the efficiency of organic solar cells.
引用
收藏
页码：1982 / 1988
页数：7
相关论文
共 50 条
  • [1] Research Progress of PEDOT: PSS Hole Transport Layer and Its Modification for Organic Solar Cells
    Zhang Y.
    Xu H.
    Zhao C.
    Cailiao Daobao/Materials Reports, 2021, 35 (03): : 03204 - 03208
  • [2] Efficiency enhancement of polymer solar cells via zwitterion doping in PEDOT:PSS hole transport layer
    Zhao, Zhiciiang
    Chen, Xiang
    Liu, Qing
    Wu, Qiliang
    Zhu, Jun
    Dai, Songyuan
    Yang, Shangfeng
    ORGANIC ELECTRONICS, 2015, 27 : 232 - 239
  • [3] Efficient and Stable Hole-Transport Material for Solar Cells: from PEDOT:PSS to Carbon Nanotubes:PSS
    Zhao, Yan
    Gao, Qing
    Yang, Dehua
    Zhang, Xuning
    Guo, Jing
    Ren, Yuke
    Chang, Xuan
    Xu, Yiming
    Yuan, Xiaoyang
    Zhang, Lu
    Zhang, Kangping
    Dai, Jianfang
    Yuan, Beihai
    Su, Chunyang
    Fang, Xin
    Song, Dengyuan
    Chen, Jianhui
    ACS ENERGY LETTERS, 2025, 10 (03): : 1439 - 1447
  • [4] Organic photovoltaic with PEDOT:PSS and V2O5 mixture as hole transport layer
    Lee, Seung Joo
    Kim, Hyeong Pil
    Yusoff, Abd Rashid Bin Mohd
    Jang, Jin
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2014, 120 : 238 - 243
  • [5] Enhancing the performance of organic solar cells by using PDINN-doped PEDOT:PSS as the hole transport layer
    Zhang, Zhenyu
    Zhang, Cai'e
    Liu, Wenlong
    Zheng, Xinming
    Chen, Qiaoling
    Yang, Chuluo
    Xu, Xinjun
    Bo, Zhishan
    POLYMER CHEMISTRY, 2024, 15 (07) : 692 - 698
  • [6] Solution Processed WO3 and PEDOT:PSS Composite for Hole Transport Layer in ITO-Free Organic Solar Cells
    Gurudevi, P.
    Venkateswari, P.
    Sivakumar, T.
    Ramesh, C.
    Vanitha, P.
    JOURNAL OF CLUSTER SCIENCE, 2023, 34 (04) : 2135 - 2145
  • [7] High-performance hole transport layer based on WS2 doped PEDOT:PSS for organic solar cells
    Wang, Yuying
    Li, Na
    Cui, Mengqi
    Li, Yuting
    Tian, Xia
    Xu, Xijie
    Rong, Qikun
    Yuan, Dong
    Zhou, Guofu
    Nian, Li
    ORGANIC ELECTRONICS, 2021, 99
  • [8] Enhanced stability and efficiency in inverted perovskite solar cells through graphene doping of PEDOT:PSS hole transport layer
    Redondo-Obispo, C.
    Ripolles, T. S.
    Cortijo-Campos, S.
    Alvarez, A. L.
    Climent-Pascual, E.
    de Andres, A.
    Coya, C.
    MATERIALS & DESIGN, 2020, 191
  • [9] Doping of Hole Transport Layer PEDOT: PSS with Pentacene for PCDTBT: PCBM Based Organic Solar Cells
    Sivakumar, G.
    Pratyusha, T.
    Gupta, D.
    Shen, W.
    MATERIALS TODAY-PROCEEDINGS, 2017, 4 (07) : 6814 - 6819
  • [10] Solution Processed WO3 and PEDOT:PSS Composite for Hole Transport Layer in ITO-Free Organic Solar Cells
    P. Gurudevi
    P. Venkateswari
    T. Sivakumar
    C. Ramesh
    P. Vanitha
    Journal of Cluster Science, 2023, 34 : 2135 - 2145
12345