Chiral materials and mechanisms for circularly polarized light-emitting diodes

被引:115
作者
Furlan, Francesco [1 ]
Moreno-Naranjo, Juan Manuel [1 ]
Gasparini, Nicola [1 ,2 ]
Feldmann, Sascha [3 ]
Wade, Jessica [2 ,4 ]
Fuchter, Matthew J. [1 ,2 ]
机构
[1] Imperial Coll London, Dept Chem, Mol Sci Res Hub, London, England
[2] Imperial Coll London, Ctr Processable Elect, London, England
[3] Harvard Univ, Rowland Inst, Cambridge, MA USA
[4] Imperial Coll London, Dept Mat, London, England
基金
欧盟地平线“2020”;
关键词
ROOM-TEMPERATURE; ELECTROLUMINESCENCE; EMISSION; POLYMER; LUMINESCENCE; ENANTIOMERS; PEROVSKITE; OLEDS;
D O I
10.1038/s41566-024-01408-z
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Circularly polarized (CP) light-emitting diodes (LEDs) hold great potential for next-generation technologies, from efficient photonic to room-temperature quantum devices. Chiral materials enable the generation of CP electroluminescence in LEDs through several different mechanisms, depending on the choice of material and device architecture. Here we summarize the mechanisms that give rise to CP electroluminescence in state-of-the-art materials, including organic small molecules, polymers, inorganic complexes and hybrid halide perovskites. We explore how the device architecture can be used to control the chiroptical properties and device performance, and suggest improvements to maximize the efficiency and dissymmetry factor of future CP LEDs. Chiral materials and related mechanisms are reviewed, with a focus on applications for circularly polarized light-emitting diodes.
引用
收藏
页码:658 / 688
页数:78
相关论文
共 103 条
[11]   Strong circularly polarized electroluminescence based on chiral salen-Zn(ii) complex monomer chromophores [J].
Chen, Yihan ;
Li, Xiaojing ;
Li, Nengquan ;
Quan, Yiwu ;
Cheng, Yixiang ;
Tang, Yanfeng .
MATERIALS CHEMISTRY FRONTIERS, 2019, 3 (05) :867-873
[12]   Perovskite Light-Emitting Diodes with External Quantum Efficiency Exceeding 22% via Small-Molecule Passivation [J].
Chu, Zema ;
Ye, Qiufeng ;
Zhao, Yang ;
Ma, Fei ;
Yin, Zhigang ;
Zhang, Xingwang ;
You, Jingbi .
ADVANCED MATERIALS, 2021, 33 (18)
[13]   Synthesis, separation, and circularly polarized luminescence studies of enantiomers of iridium(III) luminophores [J].
Coughlin, Frederick J. ;
Westrol, Michael S. ;
Oyler, Karl D. ;
Byrne, Neal ;
Kraml, Christina ;
Zysman-Colman, Eli ;
Lowry, Michael S. ;
Bernhard, Stefan .
INORGANIC CHEMISTRY, 2008, 47 (06) :2039-2048
[14]   Achieving high circularly polarized luminescence with push-pull helicenic systems: from rationalized design to top-emission CP-OLED applications [J].
Dhbaibi, Kais ;
Abella, Laura ;
Meunier-Della-Gatta, Sylvia ;
Roisnel, Thierry ;
Vanthuyne, Nicolas ;
Jamoussi, Bassem ;
Pieters, Gregory ;
Racine, Benoit ;
Quesnel, Etienne ;
Autschbach, Jochen ;
Crassous, Jeanne ;
Favereau, Ludovic .
CHEMICAL SCIENCE, 2021, 12 (15) :5522-5533
[15]   Circularly Polarized Photoluminescence from Chiral Perovskite Thin Films at Room Temperature [J].
Di Nuzzo, Daniele ;
Cui, Linsong ;
Greenfield, Jake L. ;
Zhao, Baodan ;
Friend, Richard H. ;
Meskers, Stefan C. J. .
ACS NANO, 2020, 14 (06) :7610-7616
[16]   High Circular Polarization of Electroluminescence Achieved via Self-Assembly of a Light-Emitting Chiral Conjugated Polymer into Multidomain Cholesteric Films [J].
Di Nuzzo, Daniele ;
Kulkarni, Chidambar ;
Zhao, Baodan ;
Smolinsky, Eilam ;
Tassinar, Francesco ;
Meskers, Stefan C. J. ;
Naaman, Ron ;
Meijer, E. W. ;
Friend, Richard H. .
ACS NANO, 2017, 11 (12) :12713-12722
[17]   Beyond Chiral Organic (p-Block) Chromophores for Circularly Polarized Luminescence: The Success of d-Block and f-Block Chiral Complexes [J].
Doistau, Benjamin ;
Jimenez, Juan-Ramon ;
Piguet, Claude .
FRONTIERS IN CHEMISTRY, 2020, 8
[18]   Chiral carbon dots: synthesis, optical properties, and emerging applications [J].
Doring, Aaron ;
Ushakova, Elena ;
Rogach, Andrey L. .
LIGHT-SCIENCE & APPLICATIONS, 2022, 11 (01)
[19]   Efficient up-conversion of triplet excitons into a singlet state and its application for organic light emitting diodes [J].
Endo, Ayataka ;
Sato, Keigo ;
Yoshimura, Kazuaki ;
Kai, Takahiro ;
Kawada, Atsushi ;
Miyazaki, Hiroshi ;
Adachi, Chihaya .
APPLIED PHYSICS LETTERS, 2011, 98 (08)
[20]   Theory of Chirality Induced Spin Selectivity: Progress and Challenges [J].
Evers, Ferdinand ;
Aharony, Amnon ;
Bar-Gill, Nir ;
Entin-Wohlman, Ora ;
Hedegard, Per ;
Hod, Oded ;
Jelinek, Pavel ;
Kamieniarz, Grzegorz ;
Lemeshko, Mikhail ;
Michaeli, Karen ;
Mujica, Vladimiro ;
Naaman, Ron ;
Paltiel, Yossi ;
Refaely-Abramson, Sivan ;
Tal, Oren ;
Thijssen, Jos ;
Thoss, Michael ;
van Ruitenbeek, Jan M. ;
Venkataraman, Latha ;
Waldeck, David H. ;
Yan, Binghai ;
Kronik, Leeor .
ADVANCED MATERIALS, 2022, 34 (13)