Modern Approaches to Obtaining Organofunctional Silsesquioxanes

被引:0
|
作者
Bredov, N. S. [1 ]
Kireev, V. V. [1 ]
Polyakov, V. A. [1 ]
Sokol'skaya, I. B. [2 ]
Esin, A. S. [1 ]
机构
[1] Mendeleev Univ Chem Technol, Moscow 125047, Russia
[2] State Res Inst Chem & Technol Organoelement Cpds, Moscow 111123, Russia
关键词
POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; PARTIAL ACIDOLYSIS; DENTAL COMPOSITES; RESIN COMPOSITES; DRUG-DELIVERY; ACTIVE MEDIUM; POSS; METHACRYLATE; CONDENSATION; POLYCONDENSATION;
D O I
10.1134/S181123822370039X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Modern research in the field of synthesis of organofunctional oligosilsesquioxanes is considered. Relationships between the composition and structure of oligomeric organosilsesquioxanes and the conditions for their formation during the hydrolytic and acidohydrolytic polycondensation of organotrialkoxysilanes containing various functionalities, such as methacrylic, aminopropyl, carboxyl, and cyclotriphosphazene groups, in organic radicals bonded to silicon atoms are shown. A comparative analysis of approaches to the synthesis of organofunctional incompletely condensed oligosilsesquioxanes has been carried out.
引用
收藏
页码:180 / 195
页数:16
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