Strain-Release Photocatalysis

被引：144

作者：

Bellotti, Peter ^{[1
,2
]}

Glorius, Frank ^{[1
]}

机构：

[1] Westfalische Wilhelms Univ Munster, Organ Chem Inst, D-48149 Munster, Germany

[2] Weill Cornell Med, Dept Radiol, New York, NY 10021 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2023年 / 145卷 / 38期

关键词：

LIGHT; CYCLOPROPANE; FUNCTIONALIZATION; TRANSFORMATIONS; CYCLOADDITIONS; DISCOVERY; CATALYSIS; ENERGIES; RINGS;

D O I：

10.1021/jacs.3c08206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The concept of strain in organic compounds is as old as modern organic chemistry and was initially introduced to justify the synthetic setbacks along the synthesis of small ring systems (pars construens of strain). In the last decades, chemists have developed an arsenal of strain-release reactions (pars destruens of strain) which can generate-with significant driving force-rigid aliphatic systems that can act as three-dimensional alternatives to (hetero)arenes. Photocatalysis added an additional dimension to strain-release processes by leveraging the energy of photons to create chemical complexity under mild conditions. This perspective presents the latest advancements in strain-release photocatalysis-with emphases on mechanisms, catalytic cycles, and current limitations-the unique chemical architectures that can be produced, and possible future directions.

引用

页码：20716 / 20732

页数：17

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