Effect of the Type of the Crystal Phase of In2O3 On Its Conductivity and Sensor Properties in Hydrogen Detection

被引:7
作者
Ikim, M. I. [1 ]
Spiridonova, E. Yu. [1 ]
Gromov, V. F. [1 ]
Gerasimov, G. N. [1 ]
Trakhtenberg, L. I. [1 ,2 ]
机构
[1] Russian Acad Sci, Semenov Fed Res Ctr Chem Phys, Moscow, Russia
[2] Moscow MV Lomonosov State Univ, Moscow, Russia
基金
俄罗斯科学基金会;
关键词
indium oxide; hydrothermal method; cubic and rhombohedral phases; nanoparticle; conductivity; sensor response; hydrogen;
D O I
10.1134/S199079312303003X
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Indium oxide is synthesized hydrothermally from an aqueous or alcoholic solution of indium nitrate. The phase composition and structure of the synthesized samples, as well as their conductivity and sensory response during the detection of hydrogen, are studied. A change in the conditions of hydrothermal synthesis leads to the formation of a metastable rhombohedral phase together with the main cubic phase of indium oxide. It is shown that an increase in the concentration of the rhombohedral phase in indium oxide leads to an increase in its conductivity and the maximum sensor activity for hydrogen.
引用
收藏
页码:774 / 777
页数:4
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