Influence of heat treatment on microstructure, mechanical and corrosion behavior of WE43 alloy fabricated by laser-beam powder bed fusion

被引:100
作者
Ling, Chenrong [1 ]
Li, Qiang [2 ]
Zhang, Zhe [1 ]
Yang, Youwen [1 ]
Zhou, Wenhao [3 ]
Chen, Wenlong [4 ]
Dong, Zhi [5 ]
Pan, Chunrong [1 ]
Shuai, Cijun [1 ,6 ,7 ]
机构
[1] Jiangxi Univ Sci & Technol, Coll Mech & Elect Engn, Ganzhou 341000, Peoples R China
[2] Suzhou Univ, Sch Mech & Elect Engn, Suzhou 234000, Peoples R China
[3] Northwest Inst Nonferrous Met Res, Shaanxi Key Lab Biomed Met Mat, Xian 710016, Peoples R China
[4] Gannan Med Coll, Affiliated Hosp 1, Dept Orthoped, Ganzhou 341000, Peoples R China
[5] South China Univ Technol, Sch Mech & Automot Engn, Guangzhou 510641, Peoples R China
[6] Cent South Univ, State Key Lab High Performance Complex Mfg, Changsha 410083, Peoples R China
[7] Double Med Technol Inc, Xiamen 361026, Peoples R China
基金
中国国家自然科学基金;
关键词
laser-beam powder bed fusion; WE43; alloys; heat treatment; mechanical performance; biodegradation behavior; RARE-EARTH-ELEMENTS; GRAIN-REFINEMENT; MG ALLOYS; MAGNESIUM; BIODEGRADATION; PRECIPITATION; DUCTILITY;
D O I
10.1088/2631-7990/acfad5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
WE43 parts with favorable forming quality are fabricated by laser-beam powder bed fusion and the interaction between laser beam and powder is revealed.After suitable heat treatment, the anisotropic microstructure is eliminated, with nano-scaled Mg24Y5 particles homogeneously precipitated.The yield strength and ultimate tensile strength are improved to (250.2 +/- 3.5) MPa and (312 +/- 3.7) MPa, respectively, while the elongation still maintains at high level of 15.2%.Homogenized microstructure inhibits the micro galvanic corrosion and promotes the development of passivation film, thus decreasing the degradation rate by an order of magnitude.The porous WE43 scaffolds offer a favorable environment for cell growth. Magnesium (Mg) alloys are considered to be a new generation of revolutionary medical metals. Laser-beam powder bed fusion (PBF-LB) is suitable for fabricating metal implants with personalized and complicated structures. However, the as-built part usually exhibits undesirable microstructure and unsatisfactory performance. In this work, WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment. Although a high densification rate of 99.91% was achieved using suitable processes, the as-built parts exhibited anisotropic and layered microstructure with heterogeneously precipitated Nd-rich intermetallic. After heat treatment, fine and nano-scaled Mg24Y5 particles were precipitated. Meanwhile, the alpha-Mg grains underwent recrystallization and turned coarsened slightly, which effectively weakened the texture intensity and reduced the anisotropy. As a consequence, the yield strength and ultimate tensile strength were significantly improved to (250.2 +/- 3.5) MPa and (312 +/- 3.7) MPa, respectively, while the elongation was still maintained at a high level of 15.2%. Furthermore, the homogenized microstructure reduced the tendency of localized corrosion and favored the development of uniform passivation film. Thus, the degradation rate of WE43 parts was decreased by an order of magnitude. Besides, in-vitro cell experiments proved their favorable biocompatibility.
引用
收藏
页数:18
相关论文
共 69 条
[1]   Laser additive manufacturing of biodegradable magnesium alloy WE43: A detailed microstructure analysis [J].
Baer, Florian ;
Berger, Leopold ;
Jauer, Lucas ;
Kurtuldu, Gueven ;
Schaeublin, Robin ;
Schleifenbaum, Johannes H. ;
Loeffler, Joerg F. .
ACTA BIOMATERIALIA, 2019, 98 :36-49
[2]   Promoting the columnar to equiaxed transition and grain refinement of titanium alloys during additive manufacturing [J].
Bermingham, M. J. ;
StJohn, D. H. ;
Krynen, J. ;
Tedman-Jones, S. ;
Dargusch, M. S. .
ACTA MATERIALIA, 2019, 168 :261-274
[3]   Slip mode dependency of dislocation shearing and looping of precipitates in Mg alloy WE43 [J].
Bhattacharyya, J. J. ;
Wang, F. ;
Stanford, N. ;
Agnew, S. R. .
ACTA MATERIALIA, 2018, 146 :55-62
[4]   Influence of surface finishing and heat treatments on the corrosion resistance of LPBF-produced Ti-6Al-4V alloy for biomedical applications [J].
Cabrini, M. ;
Carrozza, A. ;
Lorenzi, S. ;
Pastore, T. ;
Testa, C. ;
Manfredi, D. ;
Fino, P. ;
Scenini, F. .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2022, 308
[5]   Microstructural characteristics and crack formation in additively manufactured bimetal material of 316L stainless steel and Inconel 625 [J].
Chen, Nannan ;
Khan, Haris Ali ;
Wan, Zixuan ;
Lippert, John ;
Sun, Hui ;
Shang, Shun-Li ;
Liu, Zi-Kui ;
Li, Jingjing .
ADDITIVE MANUFACTURING, 2020, 32
[6]   The mechanisms of grain growth of Mg alloys: A review [J].
Chen, Qinghua ;
Chen, Ruinan ;
Su, Jian ;
He, Qingsong ;
Tan, Bin ;
Xu, Chao ;
Huang, Xu ;
Dai, Qingwe ;
Lu, Jian .
JOURNAL OF MAGNESIUM AND ALLOYS, 2022, 10 (09) :2384-2397
[7]   Compressive mechanical properties and shape memory effect of NiTi gradient lattice structures fabricated by laser powder bed fusion [J].
Chen, Wei ;
Gu, Dongdong ;
Yang, Jiankai ;
Yang, Qin ;
Chen, Jie ;
Shen, Xianfeng .
INTERNATIONAL JOURNAL OF EXTREME MANUFACTURING, 2022, 4 (04)
[8]   Distinction of corrosion resistance of selective laser melted Al-12Si alloy on different planes [J].
Chen, Yang ;
Zhang, Junxi ;
Gu, Xinhui ;
Dai, Nianwei ;
Qin, Peng ;
Zhang, Lai-Chang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 747 :648-658
[9]   Metastable pitting corrosion behavior of laser powder bed fusion produced Ti-6Al-4V in Hank's solution [J].
Cui, Yu-Wei ;
Chen, Liang-Yu ;
Qin, Peng ;
Li, Ruifeng ;
Zang, Qianhao ;
Peng, Jinhua ;
Zhang, Lina ;
Lu, Sheng ;
Wang, Liqiang ;
Zhang, Lai-Chang .
CORROSION SCIENCE, 2022, 203
[10]   Effects of heat treatment on microstructure and creep properties of a laser powder bed fused nickel superalloy [J].
Davies, S. J. ;
Jeffs, S. P. ;
Coleman, M. P. ;
Lancaster, R. J. .
MATERIALS & DESIGN, 2018, 159 :39-46