From waste to value-Glycerol electrooxidation for energy conversion and chemical production

Defossilation of chemical industry, aiming at reducing CO2 emissions, is constrained by the fact that many chemical products used today are carbon-based. To overcome this vi-cious circle, technologies such as the electrochemical glycerol oxidation reaction (GOR) can be used to convert glycerol, a waste product from biodiesel production, into value-added products. In a direct glycerol fuel cell, the value-added prod-ucts together with electrical energy can be generated, while in an electrolyser, the synthesis of chemicals needs to be powered by renewable energy. However, when scaling up such systems from the laboratory scale to the industrial scale, it is also essential to consider aspects such as market parameters of the potential chemical products and selectivities of the electrocatalysts. In this contribution, we aim to highlight the research opportunities regarding GOR in the context of the transition from fossil to renewable energy resources, with a particular focus on synthesizing GOR products in industrially relevant amounts.