A superior sodium-ion battery based on tubular Prussian blue cathode and its derived phosphide anode

被引：34
作者：
Jiang, Mingwei [1 ,2 ]
Ren, Lingbo [1 ,2 ]
Hou, Zhidong [1 ,2 ]
Hua, Wei [1 ,2 ]
Lei, Da [1 ,2 ]
Cao, Yunjing [1 ,2 ]
Zhang, Yu [3 ]
Wang, Jian-Gan [1 ,2 ]
机构：
[1] Northwestern Polytech Univ, Ctr Nano Energy Mat, Sch Mat Sci & Engn, State Key Lab Solidificat Proc, Xian 710072, Peoples R China
[2] Shaanxi Joint Lab Graphene NPU, Xian 710072, Peoples R China
[3] East China Univ Sci & Technol, Sch Mech & Power Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2023年 / 554卷
基金：
中国国家自然科学基金;
关键词：
Prussian blue; Phosphide; Tubular structure; Fast reaction kinetics; Sodium-ion batteries; HIGHLY EFFICIENT; PERFORMANCE; STABILITY; COMPOSITE; ANALOGS; STORAGE;
D O I：
10.1016/j.jpowsour.2022.232334
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Sodium-ion batteries are receiving incremental attention as a promising alternative of the commercial lithium-ion batteries. However, it remains a challenging task to fully explore suitable cathode and anode materials for assembling a full cell with attractive Na-ion storage properties. Herein, we demonstrate a superior sodium-ion battery by pairing a tubular Prussian blue (PB) cathode and its derived phosphide anode. The tubular configuration endows the PB with fast reaction kinetics and thus delivers a large specific capacity of 94.4 mAh g(-1) even at a high rate of 5.0 A g(-1). The PB-derived phosphide is featured by encapsulation of FeP nanoparticles into a conductive carbon matrix, which enables remarkable sodium energy storage likewise. Impressively, the as-assembled sodium-ion full cell exhibits an unprecedented capacity of 105.3 mAh g(-1) at 2.0 A g(-1) and good cycling lifespan. The present study offers a homologous design strategy based on PB and its derivatives for constructing outstanding sodium-ion full cells.
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页数：8
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