A copper(<sc>i</sc>) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

被引:4
作者
Nishiyama, Tomoki [1 ]
Kitoh-Nishioka, Hirotaka [2 ]
Tanaka, Senku [2 ,3 ]
Maekawa, Masahiko [1 ,3 ]
Kuroda-Sowa, Takayoshi [1 ]
Yoshida, Masaki [4 ]
Kato, Masako [4 ]
Okubo, Takashi [2 ,3 ]
机构
[1] Kindai Univ, Dept Chem, 3-4-1 Kowakae, Higashi Osaka, Osaka 5778502, Japan
[2] Kindai Univ, Dept Energy & Mat, 3-4-1 Kowakae, Higashi Osaka, Osaka 5778502, Japan
[3] Kindai Univ, Res Inst Sci & Technol, 3-4-1 Kowakae, Higashi Osaka, Osaka 5778502, Japan
[4] Kwansei Gakuin Univ, Sch Biol & Environm Sci, Dept Appl Chem Environm, 1 Gakuen Uegahara, Sanda, Hyogo 6691330, Japan
基金
日本学术振兴会;
关键词
Conjugated polymers;
D O I
10.1039/d3dt03125j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A coordination polymer, [Cu(SCN)(iqi)](n) (iqi = isoquinoline), containing copper(i) thiocyanate and a nitrogen-containing pi-conjugated ligand, iqi, has been synthesized and its physical properties were evaluated. This coordination polymer has a two-dimensional (2D) sheet structure consisting of copper(i) thiocyanate and shows photoluminescence derived from (MLCT)-M-3 and photoconductive properties.
引用
收藏
页码:1445 / 1448
页数:4
相关论文
共 24 条
[1]   Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20% [J].
Arora, Neha ;
Dar, M. Ibrahim ;
Hinderhofer, Alexander ;
Pellet, Norman ;
Schreiber, Frank ;
Zakeeruddin, Shaik Mohammed ;
Graetzel, Michael .
SCIENCE, 2017, 358 (6364) :768-771
[2]   Copper(I) thiocyanate networks with aromatic diimine ligands [J].
Ayala, Gerardo ;
Tronic, Tristan A. ;
Pike, Robert D. .
POLYHEDRON, 2016, 115 :257-263
[3]   Two- and three-dimensional CuSCN co-ordination networks including new CuSCN structural motifs [J].
Blake, AJ ;
Brooks, NR ;
Champness, NR ;
Crew, M ;
Hanton, LR ;
Hubberstey, P ;
Simon, PC ;
Schröder, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (16) :2813-2817
[4]   Cu(I) hybrid inorganic-organic materials with intriguing stimuli responsive and optoelectronic properties [J].
Cariati, Elena ;
Lucenti, Elena ;
Botta, Chiara ;
Giovanella, Umberto ;
Marinotto, Daniele ;
Righetto, Stefania .
COORDINATION CHEMISTRY REVIEWS, 2016, 306 :566-614
[5]   Advanced capabilities for materials modelling with QUANTUM ESPRESSO [J].
Giannozzi, P. ;
Andreussi, O. ;
Brumme, T. ;
Bunau, O. ;
Nardelli, M. Buongiorno ;
Calandra, M. ;
Car, R. ;
Cavazzoni, C. ;
Ceresoli, D. ;
Cococcioni, M. ;
Colonna, N. ;
Carnimeo, I. ;
Dal Corso, A. ;
de Gironcoli, S. ;
Delugas, P. ;
DiStasio, R. A., Jr. ;
Ferretti, A. ;
Floris, A. ;
Fratesi, G. ;
Fugallo, G. ;
Gebauer, R. ;
Gerstmann, U. ;
Giustino, F. ;
Gorni, T. ;
Jia, J. ;
Kawamura, M. ;
Ko, H-Y ;
Kokalj, A. ;
Kucukbenli, E. ;
Lazzeri, M. ;
Marsili, M. ;
Marzari, N. ;
Mauri, F. ;
Nguyen, N. L. ;
Nguyen, H-V ;
Otero-de-la-Roza, A. ;
Paulatto, L. ;
Ponce, S. ;
Rocca, D. ;
Sabatini, R. ;
Santra, B. ;
Schlipf, M. ;
Seitsonen, A. P. ;
Smogunov, A. ;
Timrov, I. ;
Thonhauser, T. ;
Umari, P. ;
Vast, N. ;
Wu, X. ;
Baroni, S. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2017, 29 (46)
[6]   QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials [J].
Giannozzi, Paolo ;
Baroni, Stefano ;
Bonini, Nicola ;
Calandra, Matteo ;
Car, Roberto ;
Cavazzoni, Carlo ;
Ceresoli, Davide ;
Chiarotti, Guido L. ;
Cococcioni, Matteo ;
Dabo, Ismaila ;
Dal Corso, Andrea ;
de Gironcoli, Stefano ;
Fabris, Stefano ;
Fratesi, Guido ;
Gebauer, Ralph ;
Gerstmann, Uwe ;
Gougoussis, Christos ;
Kokalj, Anton ;
Lazzeri, Michele ;
Martin-Samos, Layla ;
Marzari, Nicola ;
Mauri, Francesco ;
Mazzarello, Riccardo ;
Paolini, Stefano ;
Pasquarello, Alfredo ;
Paulatto, Lorenzo ;
Sbraccia, Carlo ;
Scandolo, Sandro ;
Sclauzero, Gabriele ;
Seitsonen, Ari P. ;
Smogunov, Alexander ;
Umari, Paolo ;
Wentzcovitch, Renata M. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2009, 21 (39)
[7]   A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu [J].
Grimme, Stefan ;
Antony, Jens ;
Ehrlich, Stephan ;
Krieg, Helge .
JOURNAL OF CHEMICAL PHYSICS, 2010, 132 (15)
[8]   Thiocyanato complexes of the coinage metals:: synthesis and crystal structures of the polymeric pyridine complexes [AgxCuy(SCN)x+y(py)z] [J].
Krautscheid, H ;
Emig, N ;
Klaassen, N ;
Seringer, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (18) :3071-3077
[9]   Superior performance enabled by supramolecular interactions in metal-organic cathode: the power of weak bonds [J].
Li, An-Che ;
Chang, Cheng-Han ;
Ivanov, Alexander S. ;
Lo, Yi-An ;
Popovs, Ilja ;
Chen, Jeng-Lung ;
Chuang, Yu-Chun ;
Chang, Yu-Chung ;
Chen, Bo-Hao ;
Lee, Jui-Chin ;
Chen, Teng-Hao ;
Kaveevivitchai, Watchareeya .
JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (37) :19671-19679
[10]   Robust and Highly Conductive Water-Stable Copper Iodide-Based Hybrid Single Crystals [J].
Li, Jing ;
Fang, Yang ;
Zhu, Kun ;
Teat, Simon J. ;
Reid, Obadiah G. ;
Hei, Xiuze ;
Zhu, Kai ;
Fang, Xiaochen ;
Li, Mingxing ;
Sojdak, Christopher A. ;
Cotlet, Mircea .
CHEMISTRY OF MATERIALS, 2022, 34 (22) :10040-10049